Synfacts
Issue 12 · December 2014
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A156
SYNFORM
ISSUE 2014/12
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Synthesis of Natural Products and Potential Drugs
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1233
Synthesis of Norleucosceptroids A, B, and K
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1234
Collective Synthesis of Humulanolides Using a Metathesis Cascade
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1235
Synthesis of Nominal Cycloinumakiol and Structural Revision
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1236
Synthesis of Trifluorinated Thiazolines That Target Prohibitins
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1237
Synthesis of a c-Kit Kinase Inhibitor Using Organocatalysis
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1238
Total Synthesis of (±)-Tubastrindole B
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1239
Synthesis of BMS-663068
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1240
Synthesis of Nominal Trichodermatide A
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1241
Synthesis of
Lycopodium
Alkaloids Containing Seven-Membered Rings
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1242
Synthesis of an Androgen Receptor Modulator
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1243
Divergent Total Synthesis of
Aspidosperma
Alkaloids
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Synthesis of Heterocycles
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1246
Synthesis of Imidazo-Fuzed Heterocycles via Gold-Catalyzed Cycloaddition
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1247
Inverse-Electron-Demand Diels–Alder Reaction of Asymmetric 1,2,3-Triazines
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1248
Pyridazines via an Organophosphorus-Catalyzed Diaza-Wittig Reaction
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1249
Palladium-Catalyzed Synthesis of Quinolines From Cyclopropanols
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1250
Catalyst-free Synthesis of 1-Aryltetrazoles
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1251
Synthesis of Phenanthridines from Diaryliodonium Salts and Nitriles
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1252
Synthesis of Oxazinoindoles and Pyrrolooxazines by Sc(III) Catalysis
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1253
Amidation–Oxidative Cyclization Route to 2-Aryl-2
H
-benzotriazoles
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1254
Fused Isoquinolones by Aryne/Alkyne Insertion into C–H/N–H Bonds
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1255
ArI-Catalyzed Synthesis of Benzolactones
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1256
Copper-Catalyzed Synthesis of 1-Bromoindolizines from Pyridines
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1257
Enantioselective Synthesis of Pyrrolidinones and Dihydropyridinones
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1258
A Photocatalytic Hydroamination Route to Dihydropyrazoles
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1259
Synthesis of 1,4-Thiazepin-5(4
H
)-ones without Transition Metals
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Synthesis of Materials and Unnatural Products
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1261
Pass the P
2
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1262
New Macrocycles on the Scene: O
6
-Corona[3]arene[3]tetrazines
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1263
Alkynes of Routes to Furans, Pyrroles, and Thiophenes
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1264
Fluorescent Indazoloquinazolinones by Intramolecular C−H Amination
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1265
Sequential Steps Save the Day
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1266
A Panchromatically Electrochromic Small Molecule
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1267
Expecting Silicon Valley, Finding Silicon Planar
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1268
Efficient Heteroarylation of Aromatic Amines via Dual C–H Activation
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1269
Next Time You Need a Fluorene, Try a Triazene
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1270
Climbing the Bisindeno-[
n
]thienoacene Ladder, One Rung/Ring at a Time
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1271
Air-Stable and Conductive 13-Fused-Ring Thienoacenes
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1272
Kick Your MOFs Up a Notch
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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
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1273
Fe(III)-Catalyzed Enantioselective Conia-ene Reaction
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1274
Rhodium-Catalyzed Hydroformylation of
Z
-Enamides and
Z
-Enol Esters
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1275
Iridium-Catalyzed Allylic Substitution of Silyl Dienolates
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1276
Nickel-Catalyzed Asymmetric Hydrogenation of Olefins
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1277
Asymmetric 1,4-Addition of Alkyl Groups to
N
-Sulfonyl Imines
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1278
Iron(II)-Catalyzed Intermolecular Amino-Oxygenation of Olefins
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1279
Copper-Catalyzed Enantioselective Allylic Alkylation Using Terminal Alkynes
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1280
Enantioselective Gold-Catalyzed Cyclopropanation of 1,6-Enynes
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1281
Enantioselective Trifluoromethylation of Unactivated Alkenes
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1282
Chiral Chromanes via Gold-Mediated Cyclization Employing Free Allylic Alcohols
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1283
Copper-Mediated
E
-Selective Trifluoromethylation of α,β-Unsaturated Hydrazones
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1284
Iron-Catalyzed Asymmetric Intramolecular Cyclopropanation
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1285
Asymmetric Alkene Carboamination by Palladium Catalysis
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1286
Asymmetric Synthesis of α,α-Difluoro-β-lactams
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1287
Copper-Mediated Enantioselective Hydrobromination of Styrenes
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1288
Synthesis of Chiral Pyrazolines via Chiral π-Cation Catalysis
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1289
Enantioselective Amination of Racemic Allylic Alcohols
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1290
Reverse Regioselective [4+3] Cycloaddition
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1291
Iridium-Catalyzed Enantioselective Hydrogenation of Pyridinium Salts
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1292
Palladium-Mediated Asymmetric 1,4-Addition of Diarylphosphines to
N
-Enoyl Phthalimides
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1293
Palladium-Mediated Asymmetric Decarboxylative Allylic Alkylations of α-Imino Anions
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1294
De Novo Synthesis of
P
-Stereogenic Compounds via Iridium Catalysis
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1295
Enantioselective Hydroalkoxylation of Allene Catalyzed by Palladium
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1296
Asymmetric Allylic Alkylation of Hydroxyacrylates Catalyzed by Palladium
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1297
Intramolecular Alkene Hydrosilylation Catalyzed by Rhodium
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1298
Asymmetric Alkynylation–Lactamization Cascade Catalyzed by Copper
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1299
Enantioselective Palladium and Phosphoric Acid Catalyzed Allylations of Aldehydes
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1300
Asymmetric Synthesis of Planar Chiral Ferrocenes
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1301
Asymmetric Allylic Alkylation of Azlactones with Allylic Alcohols
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Metal-Mediated Synthesis
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1303
Catalytic
gem
-Difluoropropargylation Using Aryl and Alkenyl Boron Reagents
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1304
Palladium-Catalyzed Cross-Coupling of Secondary Alkylzinc Reagents
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1305
Copper-Mediated Bis-anilide Cyclization by Double C–H/Ar–H Coupling
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1306
Enantioselective Protoboration of Disubstituted Allenes
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1307
Gold-Catalyzed Cycloisomerization to C2- and C3-Borylated Furans
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1308
Toward the
O
-Arylation of β-Hydroxy-α-Amino Acid Substrates
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1309
Cross-Coupling of Organolithium Reagents with Aryl and Vinyl Triflates
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1310
Copper-Mediated Acetoxylation
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1311
Nickel-Catalyzed Double Carboxylation
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1312
Scandium-Catalyzed [3+2] Cycloaddition of Allylsilanes to β-Silylenones
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1313
Copper-Catalyzed Silylation of Aldehydes
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1314
Three-Component Differential Vicinal Diarylation of Terminal 1,3-Dienes
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1315
Cross-Coupling of Unactivated Aryl Sulfides with Arylzinc Reagents
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1316
Reaction of Arylboronic Acids with α-Aminoesters and α-Aminoacetonitriles
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1317
Noncryogenic Boronate Rearrangement
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Organo- and Biocatalysis
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1319
Cascade [4+2] Annulation by NHC Catalysis
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1320
Phosphepine-Catalyzed Enantioselective Synthesis of Cyclopentenes
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1321
Novel Oligomeric Helical Chiral Catalysts for Asymmetric Dearomatization
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1322
Enantioselective Phase-Transfer Alkylation of Sulfenate Anions to Sulfoxides
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1323
Organocatalytic Biomimetic Synthesis of Izidine Alkaloids
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1324
Synthesis of Dicarbonyls by Combining Organocatalysis and Photoredox Catalysis
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1325
Organocatalytic Radical Addition to Alkenes
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1326
Brønsted Acid Catalyzed Enantioselective Formation of Tetrahydroxanthenes
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1327
Thiourea-Catalyzed Enantioselective Addition of Indoles to Pyrones
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1328
Asymmetric Countercation-Directed Nucleophilic Aromatic Substitutions
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1329
Enantioselective α-Amination by a BINAM-Derived Phase-Transfer Catalyst
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1330
Anion-Binding Catalysis Mediated by Pyridinium Cations
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Polymer-Supported Synthesis
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1331
Dendritic Copper Catalysts for Homogeneous Click Chemistry in Water
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1332
Ritter Reaction of Alcohols with Nitriles Using NaHSO
4
/SiO
2
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1333
Benzylic Oxidation with a Manganese Triazolate Framework
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1334
Reductive Amination of Nitriles to Tertiary Amines Using Platinum Nanowire
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1335
Reduction of Nitroarenes with NaBH
4
Using Graphene-Supported PdCu Nanoparticles
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1336
[2+2+2] Cycloaddition Using a Silica-Supported Rh–NHC Catalyst
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1337
Aerobic Oxidation and Reduction Using Pd
0
-in-UiO-67
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1338
C
3
N
4
-Catalyzed Oxidative Allylation of Tetrahydroisoquinoline Derivatives
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PDF (110 kb)
1339
The Sonogashira Coupling Using Pd
np
-nSTDP
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1340
The Sonogashira Coupling with a PS-Supported Palladium Catalyst
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1341
Direct C–H Amination of Benzothiazoles Using CuFe
2
O
4
Nanoparticles
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1342
Light-Mediated Deiodination and Cyclization Using PtNPs@TiO
2
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1343
Henry and Suzuki–Miyaura Reactions with SBA-15/CCMet and Pd Complex
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1344
Transfer Hydrogenation of Alkenes Using Ni/Ru/Pt/Au Nanoparticles
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1345
Titanosilicate Zeolite Catalyzed Selective Oxidation of Sulfides with H
2
O
2
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Erratum
1347
Direct Amination of β-Keto Esters Employing Nitrosocarbonyl Compounds
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1347
Tandem Divergent Catalysis using Nitriles
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1348
Enantioselective Carbonyl Carboacylation Initiated by C–C Bond Activation
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