DOI: 10.1055/s-00000131

Synfacts

Issue 03 · Volume 13 · March 2017 DOI: 10.1055/s-007-33458

Synform

A36
Zanda, Matteo: SYNFORM ISSUE 2017/03

Synthesis of Natural Products and Potential Drugs

z0225
All PDFs of this category
0225
Synthesis of a Key Intermediate of Omarigliptin
0226
Synthesis of (±)-Gelsedilam
0227
Syntheses of Sarcandrolide J and Shizukaol D
0228
Synthesis of (+)-Sieboldine A
0229
Syntheses of (–)-Rotenone and (–)-Dalpanol
0230
Asymmetric Cyclopropanation Using Engineered Myoglobin Catalysts
0231
Conductively Heated Sealed-Vessel Reactor: Synthesis of Olanzapine
0232
Synthesis of (+)-Mikanokryptin
0233
Synthesis of (+)-Pseudoanisatin
0234
Synthesis of (–)-Histrionicotoxin
0235
Synthesis of Idasanutlin (RG7388)
0236
Synthesis of BMS-986104

Synthesis of Heterocycles

z0237
All PDFs of this category
0237
Photoredox Nitroso-Diels–Alder Reactions
0238
Acridones by Double C–H Carbonylation of Diphenylamines
0239
A New Class of Enantiopure Oxathiazines
0240
Photochemical Stereoselective Synthesis of Azetidines
0241
Multicomponent Synthesis of Substituted 3H-1,4-Benzodiazepines
0242
Synthesis of Hexahydropyrazolo[1,5-a]-pyridines
0243
Palladium-Catalyzed Benzazetidine Synthesis with a Rationally Designed Oxidant
0244
Synthesis of Imidazo[1,5-a]pyrazin-8(7H)-ones
0245
Indole Synthesis through Dizincioindole Formation
0246
Squaramide-Catalyzed Synthesis of 3-Chroman Derivatives
0247
Chromones and Benzofurans by a Divergent Rhodium-Catalyzed Annulation
0248
An Aza-Prins Reaction in the Synthesis of Tricyclic Benzazocines
0249
Synthesis of Indazoles and Indoles from Azobenzenes through C–H Activation
0250
Trifluoromethylated 1,3,4-Thiadiazoles by [2+3] Cycloaddition
0251
Substituted Oxindoles and Dibenzoazepinones through Aryne Insertion

Synthesis of Materials and Unnatural Products

z0253
All PDFs of this category
0253
Three Benzynes and the Ynolate
0254
K-Region Annulative π-Extension with Alkynes
0255
Serendipity in the Reactions of Indole-3-carboxaldehyde with Grignard Reagents
0256
Supercharged Relay Race to Spirodiazafluorenes
0257
Reaction Update: A McMurry Coupling with Silicon
0258
Recipe for a More Aromatic Pi
0259
HF Finally Completely Trapped
0260
Gold and Ruthenium Hand in Hand
0261
Hooping it up with Furans
0262
New C–H Arylation Saves Steps for Small-Molecule Organic Semiconductors
0263
Suzuki–Miyaura Cross-Coupling of Aromatic Esters
0264
O–H/C–H Difunctionalization of Phenols

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z0265
All PDFs of this category
0265
Ruthenium-Catalyzed Asymmetric Photocycloaddition of 2′-Hydroxychalcones
0266
One-Pot Synthesis of Chiral Tricycles by Amine and Ytterbium Catalysis
0267
Asymmetric Radical Cyclopropanation of Alkenes
0268
Rhodium-Catalyzed Stereodivergent Cyclization of Allenyl Sulfonylcarbamates
0269
Diastereoselective Intermolecular Rhodium-Catalyzed Hydroalkylation
0270
Palladium-Catalyzed Asymmetric Allylic Substitution with 1,3-Dithianes
0271
Iridium-Catalyzed Asymmetric Hydrogenation of Exocyclic C=C Bonds
0272
Palladium-Catalyzed Asymmetric Synthesis of Chiral Fused Azabicycles
0273
Iron-Catalyzed Enantioselective Synthesis of BINOLs
0274
Asymmetric Arylation of Alkyl Nitriles Catalyzed by Palladium
0275
Palladium-Catalyzed Regioselective Thiocarbonylation
0276
Rhodium-Catalyzed Enantiospecific [4+3] Cycloaddition of Vinyl Aziridines and Dienes
0277
Palladium-Catalyzed Asymmetric Synthesis of Dispirooxindoles
0278
Iridium-Catalyzed Asymmetric Dearomatization of β-Naphthols with Allylic Alcohols
0279
Enantioselective Oxa-Heck Reaction of Phenols with Allylic Alcohols
0280
Ruthenium-Catalyzed Cycloisomerization of 1,6-Enediyenes
0281
Palladium-Catalyzed Asymmetric Allylic Alkylation Generating Butyrolactones
0282
Au(I)/Ni(II)-Catalyzed Stereoselective Synthesis of α-Allyl β-Keto Esters
0283
Palladium-Catalyzed Asymmetric Allylation of Allylic Acetates
0284
Photocatalytic Asymmetric Epoxidation with a Chiral Manganese Complex
0285
Development of a Palladium-Catalyzed Stereoretentive Stille Coupling Reaction
0286
Copper-Catalyzed Asymmetric [3+4] Cycloaddition of Nitrones to Azoalkenes
0287
Copper-Catalyzed Synthesis of Homoallylic Alcohols
0288
Chiral Aluminum Catalyzed Enantioselective Vinylation of Aldehydes
0289
Palladium-Catalyzed Asymmetric Mannich-Type Reaction of Dichloroacetonitrile
0290
Ruthenium-Catalyzed Asymmetric Synthesis of cis-β-Heteroaryl Amino Alcohols
0291
Stereodivergent Pd–Au Sequential Catalysis Forming Tetrahydropyrans
0292
Rhodium-Catalyzed Asymmetric Hydrogenation of Enamides

Metal-Mediated Synthesis

z0293
All PDFs of this category
0293
Csp2–Csp2 Coupling of Poly(pseudo)halogenated Arenes in Air
0294
Amination of Internal Alkynes
0295
Asymmetric Petasis Borono-Mannich Allylation
0296
Palladium-Catalyzed Cascade Reaction of Bisallenes
0297
ortho-Selective C–H Borylation of Aryl Sulfides
0298
Asymmetric Arylation of 2-Indolylacrylates
0299
Terminal Hydroboration of Branched Alkenes
0300
Synthesis of Isonitriles via One-Step Transformation of Trichloroacetamides
0301
Transformation of Homopropargyl Sulfonamides
0302
Dephosphonylation of α-Diazo-β-Carbonyl Phosphonates
0303
Reductive Nickel-Catalyzed Coupling of Enones with Alkyl Bromides
0304
Copper-Catalyzed Chan–Lam Cross-Coupling
0305
α-Arylation of α-Amino Acid Derivatives
0306
Oxidative Cross-Coupling of Arylsilanes
0307
Iron(II) Chloride Promoted Radical Cascade

Organo- and Biocatalysis

z0309
All PDFs of this category
0309
Nonnatural Reactivity of Cofactor-Dependent Enzymes upon Light Irradiation
0310
Catalytic Asymmetric Umpolung Reactions of Imines with Enones
0311
Asymmetric Catalytic Polyene Bromocyclization
0312
Optically Switchable Helicenes for an Enantiodivergent Steglich Rearrangement
0313
Cation Binding Catalysis for Enantioenriched Dioxazinanes and Dioxazepanes
0314
Large-Scale Biocatalytic Oxidation of a Sulfone to a Chiral Sulfoxide
0315
Organocatalytic Stereoselective [8+2] and [6+4] Cycloaddtions
0316
1,1,3,3-Tetratriflylpropene: A Strong Brønsted or Lewis Acid Catalyst
0317
Asymmetric Synthesis of Rauhut–Currier-type Products by Bifunctional Catalysis

Polymer-Supported Synthesis

z0319
All PDFs of this category
0319
Hydrogenations with Hydrotalcite-Supported Gold–Ceria Nanocomposites
0320
C–H and C–C Bond Activation by Iron–Silver Nanoparticles
0321
Spirocyclization of Alkyne-Tethered Indoles on Supported Silver Nanoparticles
0322
Gold-Catalyzed Aerobic Oxidative α,β-Dehydrogenation of Ketones
0323
Iridium–Porphyrin Metal–Organic Framework Catalyzed Si–H Insertion of α-Diazo Esters
0324
Controlled Reduction of Nitroarenes Catalyzed by Ruthenium Nanoparticles
0325
Synthesis of Propargylamines with Gold Nanoclusters
0326
Semihydrogenation of Alkynes to Alkenes on Silica-Supported Copper Nanoparticles
0327
Solid-Supported Alkynes for an Unsymmetrical Glaser–Hay Reaction
0328
Synthesis of Dihydropyrimidines with Ferrite-Supported Sulfonated PEG
0329
Synthesis of Quinolines on a Supported Bismuth(III) Catalyst
0330
Palladium–Nickel/Zirconia Catalyst for Hydrogenolysis of 2-Aryloxy-1-arylethanols
0331
Thiosemicarbazide–Formaldehyde Resin as a Nucleophilic Scavenger
0332
Asymmetric Ring Opening of Epoxides with a Supported Cobalt–Salen Complex
0333
Hexagonal Boron Nitride Supported Palladium Catalyst for Suzuki and Heck Reactions
0334
Chiral VO(salen) Metal–Organic Framework for Asymmetric Cyanosilylation of Aldehydes