Synfacts

Issue 08 · August 2017

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A123
SYNFORM ISSUE 2017/08 FREE ACCESS

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Synthesis of Natural Products and Potential Drugs
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0779
Total Synthesis of (–)-Flueggenine C FREE ACCESS

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0780
Synthesis of (+)-Lophirone H

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0781
Synthesis of Epacadostat FREE ACCESS

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0782
Synthesis of TEV-37440

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0783
Synthesis of (+)-Wortmannin

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0784
Regioselective Cyanomethylation of Imidazopyridines

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0785
Synthesis of an HIV-1 Protease Inhibitor

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0786
Synthesis of Flecainide

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0787
Synthesis of 2,4,5-Trisubstituted Imidazoles

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0788
Syntheses of Aurachin A and B

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0789
Total Syntheses of Lycopodium Alkaloids

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0790
Synthesis of (±)-Corymine

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0791
Synthesis of (–)-Viridin and (–)-Viridiol

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Synthesis of Heterocycles
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0793
Synthesis of C-Aryl Glycosides by Glycosyl C(sp³)–C(sp²) Stille Cross-Coupling

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0794
Niobium-Catalyzed Intramolecular Hydrofunctionalization of Alkenes

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0795
Lewis Acid Catalyzed Stereoselective Synthesis of Trisubstituted Tetrahydrofurans FREE ACCESS

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0796
Dibenzoxazepinones and -thiazepinones by Dual Copper-Catalyzed Coupling Reactions

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0797
Platinum-Catalyzed Synthesis of 2,3-Dihydro-pyrroles and Polyheterocyclic Compounds

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0798
Organocatalytic Approach to Functionalized Furans

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0799
Stereoselective Synthesis of Pyrrolidine-2,3-diones by a Claisen Rearrangement

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0800
Iron-Catalyzed Spirocyclization–Arylation

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0801
Synthesis of Pyridoimidazo-β-carbolines

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0802
Visible-Light-Induced Iron-Catalyzed Synthesis of 3,3-Disubstituted Oxindoles

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0803
Perhydroindolic Acid Catalyzed Synthesis of Chiral Tricyclic γ-Lactams

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0804
Radical Cyclization Approach to Borylated Piperidines

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0805
Synthesis of Oxazolidinones by a C–H Amination Reaction

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0806
Pyrimidines and Pyridines by Ring Expansion of Cyclobutanones

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0807
Alkylation of Amines under Mitsunobu Conditions

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Synthesis of Materials and Unnatural Products
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0809
The Power of Light in Hexadehydro-Diels–Alder Chemistry FREE ACCESS

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0810
Turning Entangled Molecules Inside Out

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0811
Tellurium-Bridged Aromatics

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0812
Bridged with Sulfur and Silicon: New Hetero[8]circulenes

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0813
There’s More than One Way to Form Corona[5]arenes

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0814
Donor–Acceptor Nanohoops

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0815
A Radically New Rearrangement

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0816
Supramolecularly-Catalyzed Knoevenagel Condensation

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0817
Tetracene Dimers Exploring the World of SF (Singlet Fission)

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0818
A Pyrene-Capped N-Heteroacene

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0819
Direct Allylic/Benzylic C–H Alkylation

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0820
Cross-Conjugated [36]Octaphyrins

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
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0821
Silver-Catalyzed Intermolecular Bromotrifluoromethoxylation of Alkenes FREE ACCESS

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0822
Stereoselective Cyclizations of Allylic Alcohols

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0823
Regioselective Palladium-Catalyzed Alkynylation of Enallenes FREE ACCESS

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0824
Palladium-Catalyzed Asymmetric Three-Component Coupling Reaction

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0825
Iridium-Catalyzed Diastereoselective Allylation of Glycidols

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0826
Ruthenium-Catalyzed Asymmetric Hydro-genation of Nitrogen-Containing Heterocycles

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0827
Enantioselective Copper-Catalyzed Aminoarylation of Styrenes

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0828
Nickel-Catalyzed Semihydrogenation of Alkynes by Sodium Borohydride

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0829
Silver and Amine Co-catalyzed Desymmetrization of Cyclohexanones

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0830
Hypervalent Iodine Reagents for the Selective Perfluoroalkyltriflation of Alkynes

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0831
Rhodium-Catalyzed Enantioselective Oxidative Cyclization

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0832
Iridium-Catalyzed Asymmetric Hydrogenation through Dynamic Kinetic Resolution

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0833
Ruthenium-Catalyzed Asymmetric Hydrogenation of β-Acetamidovinyl Sulfides

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0834
Copper-Catalyzed Enantioselective [3+1] Cycloaddition Reaction

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0835
Rhodium-Catalyzed Enantioselective Synthesis of β′-Aryl Enones

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0836
Regioselective Nickel-Catalyzed Hydrocarboxylation of Ynamides

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0837
Enantioselective Iridium-Catalyzed Synthesis of Tetrahydroquinolines

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0838
One-Pot Cascade Reaction to Form gem-Diarylbenzofuran-3(2H)-ones

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0839
Rhodium-Catalyzed Enantioselective Conjugate Addition of Electron-Rich Alkenes

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0840
Synthesis and Applications of Chiral Monophosphine Ligands

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0841
Iridium-Catalyzed Enantioselective Borylation Reaction

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0842
Asymmetric Copper- or Iron-Catalyzed Intramolecular Cyclopropanation

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0843
Asymmetric Hydroarylation of Phospholene Oxides through Dynamic Kinetic Resolution

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0844
Transition-Metal-Catalyzed Addition of 4-Pyridones to Allenes

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0845
Iridium-Catalyzed Enantioselective Hydroarylation

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0846
Rhodium-Catalyzed Ring Opening of Stereodefined Vinyl Aziridines

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0847
Nickel–Bis(oxazoline)-Catalyzed Enantioselective [3+2] Cycloaddition

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0848
Lipase/Iron-Catalyzed Dynamic Kinetic Resolution of Secondary Alcohols

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0849
Utilizing Dynamic Kinetic Resolution in Asymmetric Dihydroxylation

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0850
Asymmetric Decarboxylative [4+2] Cyclization

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Metal-Mediated Synthesis
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0851
Palladium-Catalyzed Decarbonylative Cyanation

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0852
Iridium-Catalyzed para-Selective Borylation of Aromatic Esters

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0853
Palladium-Catalyzed Chemoselective Alkylation of Aryl Bromides

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0854
Copper-Catalyzed Stereoselective Borylation

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0855
Sulfone–Metal Exchange

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0856
Anionic Fries-Type Rearrangements in Flow

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0857
Domino Hydroboration/Trifluoromethylation

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0858
Copper-Catalyzed Arylation of Benzylic C–H Bonds

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0859
Activation of Earth-Abundant Metal Catalysts Using Sodium tert-Butoxide

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0860
Catalytic Enantioselective Preparation of Tertiary Alcohols

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0861
Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides

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0862
Iridium-Catalyzed ortho-Borylation of Phenols

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0863
Copper-Mediated ¹¹C-Aromatic Cyanation

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0864
Vinyl Azide Enolate [3+2] Cycloaddition

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Organo- and Biocatalysis
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0865
NHC-Catalyzed Oxidative [4+2] Annulation of 2-Hydroxybenzaldehydes and Ketones

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0866
Chiral Fullerene-Derived Thioureas as Recyclable Asymmetric Organocatalysts

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0867
Catalytic Stereoselective Synthesis of Pronucleotides FREE ACCESS

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0868
A Shuttling Strategy for the Enantioselective β-Protonation of Enals

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0869
Enantioselective Photoorganocatalytic Formal α-Alkylation of Aldehydes

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0870
Total Synthesis of (+)-Rishirilide B through Oxidative Kinetic Resolution

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0871
Chemoenzymatic Route to Chiral Gamma Secretase Inhibitor Intermediates

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0872
Chiral Phosphoric Acid Catalyzed Kinetic Resolution of 2-Pyridyl Esters

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0873
Construction of a Quaternary Carbon by a Mannich Reaction

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0874
Direct Hydroxylation of Benzene to Phenol by Cytochrome P450BM3

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0875
N-Heterocyclic Carbene Catalyzed Oxidative Spirocyclization of Indoles

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Polymer-Supported Synthesis
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0877
Parallel Kinetic Resolution of N-Heterocycles by N-Acylations in Flow FREE ACCESS

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0878
Aerobic Oxidation of Aralkanes on Carbon Nanotube Supported Cobalt

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0879
Suzuki Coupling on Eumelanin-Supported Palladium Nanoparticles

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0880
Dehydrogenative Aromatization on a Ni–Mg–Al Layered Hydroxide-Supported Pd Catalyst

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0881
Controlled Hydrogenation of Alkynes on Polymer-Coated Palladium Nanoparticles

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0882
Graphene Oxide/NHC–Supported Pd Catalyst for Cross-Couplings in Water

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0883
Silver Nanoparticle Catalyzed Carboxylation of Alkynes with Carbon Dioxide

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0884
Friedel–Crafts Alkylation of Indoles with 3-Indolylmethanols

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0885
Sonogashira Cross-Coupling on N,N-DMF-Stabilized Copper Nanoparticles

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0886
Synthesis of Benzothiazoles by Using a Polythiazolium Catalyst

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0887
Tsuji–Trost Allylation with Palladium Nanoparticles in Water

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0888
Semihydrogenation of Alkynes on Ti- or Zr-Supported FeO_x Nanoparticles

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0889
Strecker Reaction with Sulfated Polyborate

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0890
Hydrochlorination of Alkynes with Titania-Supported Gold Nanoparticles

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0891
Synthesis of Carbonates with Phosphonium-Based Polyionic Liquids

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0892
Acidic Zeolite Supported Ruthenium for Selenofunctionalization of Alkenes

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0893
Gold-Catalyzed Synthesis of 2,5-Disubstituted Oxazoles

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