DOI: 10.1055/s-00000131

Synfacts

Issue 05 · Volume 19 · May 2023 DOI: 10.1055/s-013-57327

Synform

  • A79

    SYNFORM ISSUE 2023/05

    • Synthesis of Natural Products

  • z0427

    All PDFs of this category

  • 0427

    Synthesis of (±)-Vilmoraconitine

  • 0428

    Synthesis of (+)-Kopsaporine

  • 0429

    Total Synthesis of (+)-Isoneoamphilectane

  • 0430

    Synthesis of (+)-Epiibogamine

  • 0431

    Total Synthesis of (+)-Zizaene

  • 0432

    Total Synthesis of (+)-Stephadiamine

  • 0433

    Synthesis of (±)-Ingenol

    • Synthesis of Heterocycles

  • z0435

    All PDFs of this category

  • 0435

    NHC-Mediated Synthesis of γ-Lactams

  • 0436

    Organocatalytic Cloke–Wilson Rearrangement to Access Multi-Substituted Furans

  • 0437

    Copper-Catalyzed Benzylic sp3 C–H Oxidative Annulation of Ketones and Amines

  • 0438

    Robust Synthesis of Functionalized Bicyclic Heteroaromatic Sulfonyl Fluorides

  • 0439

    Ruthenium-Catalyzed Synthesis of Piperazines and Diazepanes

  • 0440

    Zn-Mediated Synthesis of Pyridines from Alcohols

  • 0441

    Practical Arynes from Unfunctionalized Arenes

  • 0442

    Versatile Synthesis of 4-Iodopyrrole-2-carbaldehydes

  • 0443

    Improved Synthesis of the DLK Inhibitor GDC-0134

  • 0444

    Savie: A Biodegradable ‘Drop-In’ Surfactant Replacement for TPGS-750-M

  • 0445

    Transformations of Aliphatic Amines and Anilines into Diverse Functionalities

  • 0446

    One-Pot Synthesis of N-Functionalized Indoles through a Three-Step Tandem Process

  • 0447

    Aerobic Oxidative Cycloaddition Reactions for Pyrazole Synthesis

    • Synthesis of Materials and Unnatural Products

  • z0449

    All PDFs of this category

  • 0449

    From Biphenyl Triflate to Fluorene

  • 0450

    Remote C–H Functionalization on Stacked Aromatics

  • 0451

    Expanded [23]-Helicene

  • 0452

    Hypervalent Iodine Put to Use

  • 0453

    Versatile Syntheses of Crowded Trisphosphines

  • 0454

    A New T-Type Molecular Photoswitch

  • 0455

    Light-Induced Radical-Mediated Minisci Alkylation

  • 0456

    Seven- to Eight-Membered Polyene Ring Expansion

  • 0457

    The Role of Counteranion in Rhodium Catalysis

  • 0458

    One-Pot Synthesis of Degradable Block Copolymers

  • 0459

    Radical-Polymerizable Masked Vinylboronic Acids

  • 0460

    Room-Temperature C–N Coupling

    • Metals in Synthesis

  • z0461

    All PDFs of this category

  • 0461

    Cutting Me Off: Selective N-Demethylation of Trialkylamines Using C(sp2)–Bromides as HAT Reagents

  • 0462

    Synthesis of C-4 Substituted Indoles via Pd-Catalyzed Decarbonylative Cyclization

  • 0463

    Highly E- and Z-Selective Hydrogenation of Alkynes Using Chromium and Cyclic Carbene Ligands

  • 0464

    Copper-Catalyzed Carbophosphonylation of Styrenes

  • 0465

    Pt/Zn-Catalyzed Diborylation of Propargylic Amines

  • 0466

    Allylic C(sp3)–H Functionalization of Propylene and Alkenes Catalyzed by a Cationic Iron(II) Complex

  • 0467

    Nickel/Photoredox-Catalyzed C(sp3)–H Arylation in the γ-Position of Sulfamate Esters and Amides

  • 0468

    Mono-ortho-Alkylation of Meta-Substituted Iodoarenes Using a Cycloolefin Ligand in a Catellani-Type Reaction

  • 0469

    Palladium-Catalyzed Rearrangement of 3-Arylcyclobutanones to 1-Indanones

  • 0470

    Synthesis of Skipped Trienes via Ni-Catalyzed Bis-Allylation of Alkynes

  • 0471

    Rhodium-Catalyzed [4+2+1] Annulation Harnessing the Strain Release of a Methylenecyclopropyl Group

  • 0472

    Samarium(II) Iodide-Catalyzed Formal [2π+2σ] Cycloaddition of Bicyclo[1.1.0]butyl Ketones and Alkenes

  • 0473

    Dearomative Carboxylation of (Hetero)Arenes with Cesium Formate under Dual Photoredox/HAT Catalysis

  • 0474

    Desulfonylative Cross-Electrophile Coupling of Aryl Sulfones and Aryl Bromides under Nickel Catalysis

  • 0475

    Nickel-Catalyzed Carbonylation of Alkyl Halides to Acyl Chlorides under Blue Light Irradiation

  • 0476

    Pd-Catalyzed Arylation of Furans and Pyrroles Facilitated by Remote Carbonyl Groups

  • 0477

    Synthesis of Functionalized Nitriles using a Nickel-Catalyzed Substitution of Allylic Alcohols

  • 0478

    Copper-Catalyzed Enantioconvergent C(sp3)–P Cross-Coupling of Secondary Benzyl and Propargyl Bromides

  • 0479

    Installation of the Magic Methyl Group onto Heterocycles by Dual Decatungstate Photo-/Nickel Catalysis

  • 0480

    Palladium-Catalyzed Enantioselective Synthesis of α-Alkenyl-Substituted 2,3-Dihydrobenzofurans

  • 0481

    Synthesis of Thioethers via Ni-Catalyzed Cross-Coupling of Alkyl Thiols with Aryl or Alkenyl Triflates

  • 0482

    Enantioselective Synthesis of Allylsilanes by Nickel-Catalyzed Hydrosilylation of 1,1-Disubstituted Allenes

  • 0483

    Nickel-Catalyzed Synthesis of Enantioenriched Tertiary Alcohols via DyKAT Processes

  • 0484

    Ligand-Controlled Stereodivergent Allylic C(sp3)–H Arylation under Dual Photoredox/Nickel Catalysis

  • 0485

    Copper-Catalyzed Enantioselective Dienolate Additions to Aldehydes

  • 0486

    Palladium-Catalyzed [4+2] Annulation to Access [6.7]-Fused N-Heterocycles

  • 0487

    The Fürstner Indole Synthesis: Titanium-Catalyzed Intramolecular McMurry-Type Carbonyl Coupling

    • Polymer-Supported Synthesis

  • z0489

    All PDFs of this category

  • 0489

    Photocatalytic Dehydrogenative Amination of Cyclohexanones

  • 0490

    Hydrogenation of Benzofurans, Indoles, and Benzothiophenes by Co/Co3O4 Core-Shell NPs on Silica

  • 0491

    Oxidative Transformation of Silanes Using a Cobalt Catalyst, Supported on N-Doped Porous Carbon

  • 0492

    Asymmetric Michael Addition Catalyzed by Chiral-Diamine-Modified Ni Nanoparticles on SiO2

  • 0493

    Aziridination and Oxyamination of Styrenes with a Single-Atomic Cobalt Catalyst

  • 0494

    Oxidative Coupling of Phenols and Alkenylphenols with TiO2 under Visible Light Irradiation

  • 0495

    Exhaustive Hydrogenation of Esters and Carboxylic Acids to Alkanes with a Heterogeneous Pt Catalyst

  • 0496

    Semihydrogenation of Alkynes Promoted by a 2D Palladium Metallenes Loaded on Niobium Carbide

  • 0497

    Enantioselective Synthesis of Quaternary Tryptolines by a Polystyrene-Supported Phosphoric-Acid Catalyst

  • 0498

    Nanocrystal Facet Effects of Ceria in Pd/CeO2 Catalysts for Oxidation of Benzyl Alcohols

  • 0499

    β-Selective Furanosylation of α-Furanosyl Fluoride Donors Inside Resorcin[4]arene Supramolecular Capsule

    • Organo- and Biocatalysis

  • z0501

    All PDFs of this category

  • 0501

    Visible-Light Photocatalysis Enables Anti-Markovnikov Hydrofunctionalization of α-Olefins

  • 0502

    Breaking Symmetry: Dynamic Kinetic Resolution Enables Organocatalytic Synthesis of Dual-Axial Compounds

  • 0503

    Transition-Metal-Mimicking Behavior of New Cationic Constrained Phosphine Species

  • 0504

    Chiral Phosphoric Acid Permits Desymmetrizing Hydrolysis of Oxidatively Generated S(VI) Dichlorides

  • 0505

    Peptide Catalysis Permits Asymmetric Conjugate Addition of Aldehydes to α-Substituted Vinyl Triflones

  • 0506

    Aldol-Type Reaction of α,α-Difluoromethyl Ketones Catalyzed by an Organosuperbase

  • 0507

    Dual-Role Disulfide-Catalyzed Intramolecular Hydroamination through N–H Activation

  • 0508

    Imine Reductase for the Synthesis of Pharmaceutically Relevant Amines

    • Innovative Drug Discovery and Development

  • z0509

    All PDFs of this category

  • 0509

    Bicycloheptanes as meta-Substituted Arene Bioisosteres

  • 0510

    Utilizing Kinetic Modeling for the Conservative Prediction of Dialkyl-N-Nitrosamine Formation

  • 0511

    Synthesis of Novel (±)-Lysergic Acid Derivative 12-Chlorolysergic Acid

  • 0512

    Aptamer-LYTACs Access Tissue-specific Targeted Degradation

  • 0513

    Chemoenzymatic Synthesis of Cepafungin I and Its Analogs

  • 0514

    Enantioselective Synthesis of Drug Precursors by Photo-HAT and Facially Selective Radical Capture

  • 0515

    Continuous-Flow Process For Safe Formation and Direct Use of Aryldiazoacetate in Cyclopropanation

  • 0516

    Introduction of a Potent and Selective JNK2 Inhibitor

  • 0517

    Shining Light on Aryl Nitrenes

  • 0518

    General BCP-Wing C–H Activation and Rapid Access to Diverse Bridge-Substituted Arene Bioisosteres

  • 0519

    Ultralow Band Gap Conjugated Polymers Serve As Photothermal Therapeutic Agents

  • 0520

    Synthesis Confirming Structure: The Lobelia Alkaloids

    • Peptide Chemistry

  • z0521

    All PDFs of this category

  • 0521

    Ir-Catalyzed Enantio- and Diastereoselective Synthesis of 3-Substituted Proline Derivatives

  • 0522

    Iodide-Mediated Amidation Reaction under Electrochemical Conditions

  • 0523

    Photochemical Synthesis of Unnatural Amino Acids through CF3 Radical Addition to Michael Acceptors

  • 0524

    Synthesis of Quaternary-Substituted α-Amino γ‑Butyrolactams

  • 0525

    Pd and Cu Synergistic Catalysis for the Synthesis of α,α-Disubstituted Amino Acids

  • 0526

    Synthesis of Fluorinated Non-Canonical Peptides from α-Fluorinated Carboxylic Acid

  • 0527

    β,γ,δ,ε-Amino Acid Synthesis by Photocatalytic Carboxylation with CO2

  • 0528

    Arylation of Short Peptides Using a Palladium Catalyst

  • 0529

    Deprotection of 2,2-Dimethyl-2-(o-nitrophenyl)acetyl (DMNA) Group in Amino Acids and Peptides

    • Flow Chemistry

  • z0531

    All PDFs of this category

  • 0531

    Effects of Different Substituents on the Regioselectivity of a Photocascade Reaction in Continuous Flow

    • Erratum

  • 0532

    Erratum: Cu-Catalyzed Hydrogermylation of Dehydro Amino Acids