DOI: 10.1055/s-00000131

Synfacts

Ausgabe 05 · Volume 20 · Mai 2024 DOI: 10.1055/s-014-59482

Synform

  • A071

    SYNFORM ISSUE 2024/05

    • Synthesis of Natural Products

  • z0447

    All PDFs of this category

  • 0447

    Total Synthesis of (–)-Hunterine A

  • 0448

    Syntheses of (–)-Nidulalin A and (–)-Nidulaxanthone A

  • 0449

    Total Synthesis of Securamine D

  • 0450

    Synthesis of (+)-Principinol B

  • 0451

    Total Synthesis of (–)-Psammaplysin A

  • 0452

    Total Synthesis of (+)-Penicibilaenes A and B

  • 0453

    Synthesis of (±)-Gelsemine

    • Synthesis of Heterocycles

  • z0455

    All PDFs of this category

  • 0455

    Spiro-Substituted Dioxetane-Based Chemical Probes with Enhanced Detection and Sensitivity Limits

  • 0456

    Palladium-Mediated Diastereoselective Functionalization of Cyrene

  • 0457

    Mild Nitrogen-to-Carbon Transmutation of Azaarene N-Oxides

  • 0458

    Using Metallaphotoredox Towards the Synthesis of Aryl Nitriles and α-Aryl Nitriles

  • 0459

    Access to and Physicochemical Analysis of Fluorinated Saturated Bicyclic Amine Building Blocks

  • 0460

    Synthesis of Quinolones from Propargylic Chlorides and Amines

  • 0461

    Electrochemical Formal C–H/C–H Regioselective Coupling of Heteroarenes

  • 0462

    Copper-Catalyzed Synthesis of N-Heterocyclic Bicycles

  • 0463

    Skeletal Editing of Pyridines to Afford 1,2-Diazepines

  • 0464

    Electrochemical Cross-Dehydrogenative of Amides and Heteroarenes

  • 0465

    Tether-Controlled Regiochemical Access to Complex Polyheterocyclic Molecular Architectures

    • Synthesis of Materials and Unnatural Products

  • z0467

    All PDFs of this category

  • 0467

    First Stable σ0π2 Carbene

  • 0468

    BN-Heterocycles from N-Heterocycle Editing

  • 0469

    Stabilizing Acenes with Macrocycle Shielding

  • 0470

    Biaryl Ligation Promoted by Catalyst-based π–π Stacking

  • 0471

    Unsymmetric Macrocycle from Post-Modification of Dynamic Covalent Synthesis

  • 0472

    Metalla-dehydro[11]annulenes from [10+1] Reactions

  • 0473

    Azahomocorannulene Cation and Radical

  • 0474

    Convertible Polyphenylene Covalent Organic Frameworks

  • 0475

    Single-Crystal Ladder Polymer with Double Dynamic Covalent Linkers

  • 0476

    Heptagon-embedded Highly Curved Diaza[7]helicenes

  • 0477

    Acid-Triggered RAFT Polymerization

  • 0478

    Spirobifluorenes from Biaryls and Fluorenones

    • Metals in Synthesis

  • z0479

    All PDFs of this category

  • 0479

    Hydrohalogenation of Alkenes Using Collidine·HX Salts under Dual Cobalt and Photoredox Catalysis

  • 0480

    Hydrofluorination of Alkenes Using Et3N·HF under Dual Cobalt and Photoredox Catalysis

  • 0481

    Stereoselective Cu-Catalyzed Hydroborylation and Hydrosilylation of Spirocyclopropenes

  • 0482

    Making Allylamines by 1,4-Aminoarylation of Butadienes under Photoinduced Palladium Catalysis

  • 0483

    Cross-Electrophile Coupling Enabled by Visible-Light Palladium Catalysis

  • 0484

    Copper-Catalyzed Crystallization-Induced Deracemization of Atropisomeric BINOL Derivatives

  • 0485

    Cobalt-Catalyzed Hydrogenation and Deuteration of Bicyclic Olefins

  • 0486

    Copper-Catalyzed Cross-Coupling of Benzyl Halides with (Me4N)SCF3

  • 0487

    Asymmetric Synthesis of α-Aryl Amides Using Nickel/Photoredox Catalysis

  • 0488

    C(sp3)–H Borylation of Alkanes and Silanes under Photoelectrochemically Driven Iron Catalysis

  • 0489

    Dialkylation of Alkenes with Aliphatic Alcohols and Alkyl Halides by Dual Nickel and Photoredox Catalysis

  • 0490

    Visible Light/Cu-Catalyzed Four-Component Alkene Azido­sulfonylation Using DABSO and Arylthianthrenium Salts

  • 0491

    Cobalt-Catalyzed Hydrosilylation of 1,6-Diynes via an Oxidative Cyclization

  • 0492

    Iridium-Catalyzed Asymmetric Silylation of Propargylic C(sp3)–H Bonds

  • 0493

    Asymmetric Synthesis of 1,3-Cyclohexadienes Enabled by Pd/Chiral Phosphoric Acid Cooperative Catalysis

  • 0494

    Azidation and Etherification of Remote C(sp2)–C(sp3) Bonds of Amines Involving 1,4-Aryl Migration

  • 0495

    Access to Axially Chiral N‑Arylindoles via Palladium-Catalyzed Atroposelective Larock Indole Synthesis

  • 0496

    Access to Highly Functionalized Cyclohexanes via a Silver-Catalyzed Double Desymmetrization

  • 0497

    Asymmetric α-C(sp3)–H Allylic Alkylation of Primary Alkylamines by Merging Iridium and Ketone Catalysis

  • 0498

    Ni-Catalyzed Electroreductive Decarboxylative Cross-Coupling of Redox-Active Esters and Oxime Esters

  • 0499

    Synthesis of N-Aryl Sulfonamides Enabled by Visible-Light Nickel Catalysis

  • 0500

    Synthesis of C(sp3)-Rich Carbonyl-Containing Scaffolds via Ni-Catalyzed Deaminative Alkyl-Alkyl Cross-Coupling

  • 0501

    Merging Decatungstate-Photocatalyzed Carbonylation of Alkanes and Asymmetric Brønsted Acid Catalysis

  • 0502

    Deoxygenative Coupling of Carbonyl Compounds with Alkynes under Molybdenum Catalysis

  • 0503

    Pd-Catalyzed Synthesis of Hydropyrrole-Containing Spirocycles via Domino Isonitrile Insertion/Heck Reactions

  • 0504

    Asymmetric Photocycloaddition of 2-Acetonaphthones

  • 0505

    Cobalt-Mediated Intramolecular Cyclization of Bis-homoallylic Alcohols under Aerobic Conditions

    • Polymer-Supported Synthesis

  • z0507

    All PDFs of this category

  • 0507

    Oxidative Homo-Coupling of Benzyamines Using Multi-Motif Molecule-Based COFs

  • 0508

    Oxidation, Halogenation and Diels–Alder Reaction Promoted by a Covalent Triazine Framework

  • 0509

    Asymmetric α-Arylation of Aldehydes with Aminophenol by 2D Chiral COF

  • 0510

    N-Alkylation of Primary Amides with Alcohols Catalyzed by Cobalt Nanoparticles

  • 0511

    Low-Valent Platinum Single-Atom Catalyst for Hydrosilylation of Alkenes

  • 0512

    Selective Hydrogenation of Benzofurans Catalyzed by Pd–Ru Bimetallic Nanoparticles

  • 0513

    Hydrogenation of Chlorobenzenes and Nitrobenzenes Using Au–Pd Bimetallic NPs Supported on COF

  • 0514

    Quinoline-Linked COF for the Photocatalytic Oxidative Decarboxylation and Homo-Coupling Reactions

  • 0515

    C–O, C–S, and C–P Coupling of Aryl Halides by a Ni(II)-Incorporated Covalent Organic Framework

  • 0516

    Photoreduction of Nitrogroups via a Self-Assembled TiO2-TEOA-Nitroarenes Complex

  • 0517

    Trisindole Synthesis through a Graphene Oxide-Catalyzed Carbene-Transfer Reaction

    • Organo- and Biocatalysis

  • z0519

    All PDFs of this category

  • 0519

    Organocatalytic Nucleophilic Desymmetrization of P(V) Precursors

  • 0520

    Flavin-Photocatalytic Sulfide α-C–H Functionalization Using Arylsulfonyl Multiple-Bond Reagents

  • 0521

    Diazaphospholene Hydrides Catalyze Enantioselective Reductive Eschenmoser–Claisen Rearrangements

  • 0522

    Organocatalytic Photoinduced Diastereoselective 1,2-Sulfonylsulfination of Alkenes

  • 0523

    Regiodivergent Radical Termination for Intermolecular Biocatalytic C–C Bond Formation

  • 0524

    Stereoselective Synthesis of α-Aminonitriles, Catalyzed by Hydrogen-Bonding Donors

  • 0525

    Enzymatic Cleavage of Silicon–Carbon Bonds in Siloxanes

  • 0526

    Mesoionic N-Heterocyclic Olefin Catalyzes Formylation of Thiols via CO2 Trapping

  • 0527

    Enantioselective Control Over α-Iminonitriles with a Novel Bifunctional Superbase-Thiourea Organocatalyst

    • Innovative Drug Discovery and Development

  • z0529

    All PDFs of this category

  • 0529

    A Convergent and Short Synthesis of Sorbicillactone A

  • 0530

    Brain Biodistribution in Non-Human Primates of [11C]BIIB104, an AMPA Receptor PAM

  • 0531

    CVN766, the Selective Orexin-1-Receptor Antagonist Progressed to Clinical Investigations

  • 0532

    One-Pot, Palladium-Free Access to 1° and 2° Amines

  • 0533

    Access to Buchwald–Hartwig Products by ‘NH’ Insertion of Suzuki–Miyaura Aryl Partners

  • 0534

    Arenophile Cycloaddition-Mediated Dearomative Pyridine Oxidation

  • 0535

    Converting 14N-Pyridines to 15N-Pyridines through Zincke Imine Intermediates

  • 0536

    From Racemic Mixtures to Enantioenriched Molecules: Suzuki–Miyaura Arylation of Acyclic Allylic Systems

  • 0537

    Accelerated Photochemical Reactions at Oil-Water Interface Exploiting Melting Point Depression

  • 0538

    Carbene-Catalyzed Alkylation of Indoles

  • 0539

    A Mild Sulfation Strategy for Alcohols

  • 0540

    Organo-Click Reaction Enables Access to Anti­malarial Derivatives of Artemisinin

  • 0541

    Parallel Synthesis of PROTACs via Photochemical C(sp2)–C(sp3) Cross-Coupling

  • 0542

    An Asymmetric Synthesis of Sulfoximines, Sulfonimidamides and Sulfonimidoyl Fluorides

  • 0543

    Schwartz’s Regent as a Chemo- and Diastereoselective Reductant of Sulfinyl Ketimines to Yield Chiral Amines

  • 0544

    Total Synthesis and SAR Studies of the Neurotrophic Sesquiterpenoid Jiadifenin

    • Peptide Chemistry

  • z0545

    All PDFs of this category

  • 0545

    Dehydrative Peptide Coupling Promoted by HBF4/MS 5Å

  • 0546

    Synthesis of Functionalized Amino Acids from Cysteine Pentafluoropyridine

  • 0547

    Chiral Ru-Li Combined Catalysts for Asymmetric Cyanation of α-Ketimino Ester Derivatives

  • 0548

    Unprotected Cyclic Peptide Methylene Dithioacetals Synthesis by Rhodium Catalysis

  • 0549

    Synthesis of α,α-Dialkyl Amino Acid Ethyl Esters Using Asymmetric Phase-Transfer Alkylation

  • 0550

    Copper-Catalyzed C(sp3)–H Alkylation of Glycine Derivatives

  • 0551

    Activation of N-Ts Amide C–N Bonds by N-Heterocyclic Carbene-Squaramide Bifunctional Catalyst

  • 0552

    One-Pot Protocol to Access Spirocyclic Unnatural β-Amino Acids via C–H Activation/C–C Cleavage

  • 0553

    Synthesis of β-Tertiary Amino Acids Analogues via Cobalt-Catalyzed Stereoselective Radical Addition

  • 0554

    Copper-Catalyzed [3+2] Cycloaddition for the Site-Specific Modification of Peptides

  • 0555

    Photoredox and Nickel-Catalyzed Glycosylation of Amino Acids and Peptides

  • 0556

    Synthesis of Optically Active Amino Amides

  • 0557

    Racemization-Free Synthesis of N-Formyl Amino Acid Esters

    • Flow Chemistry

  • z0559

    All PDFs of this category

  • 0559

    Synthesis of Pentafluorosulfanylpyrazoles in Flow