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Synthesis 1995; 1995(3): 245-247
DOI: 10.1055/s-1995-3911
short paper
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Vinylation of Benzylic Quaternary Ammonium Salts Catalyzed by Palladium

Pan Yi, Zhang Zhuangyu* , Hu Hongwen
  • *Department of Chemistry, Nanjing University, Nanjing 210008, People’s Republic of China
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Publication Date:
31 December 2000 (online)

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The palladium-catalyzed vinylation of benzylic tributylammonium salts with a variety of olefins has been studied. A possible free radical mechanism is proposed.

vinylation - quaternary ammonium salts - palladium acetate - catalysis - hydrogenation