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Synthesis 2002(15): 2177-2182
DOI: 10.1055/s-2002-34837
DOI: 10.1055/s-2002-34837
PAPER
© Georg Thieme Verlag Stuttgart · New YorkFacile Syntheses of 4-(2-Cyanoethylthio)-1,3-dithiole-2-thione and New Electron Donors with Two TTF Units and Compounds with Bis(1,3-dithiole-2-thione) Groups
Weitere Informationen
Received
30 April 2002
Publikationsdatum:
21. Oktober 2002 (online)
Publikationsverlauf
Publikationsdatum:
21. Oktober 2002 (online)
Abstract
The synthetic conditions for the preparation of 4-(2-cyanoethylthio)-1,3-dithiole-2-thione (1) from TBA2·[Zn(dmit)2] were studied. Compound 1 was used to synthesize new electron donors with two tetrathiafulvalene (TTF) units. Other interesting compounds that are good precursors for tetrathiafulvalenophanes were also easily prepared from TBA2·[Zn(dmit)2].
Key words
electron donors - tetrathiafulvalene - cyclophane - 1,3-dithiole-2-thione - 1,3-dithiole-2-thione-4,5-dithiolate
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