A Novel Three-Component Reaction of Triphenylphosphine, DMAD, and Electron-Deficient Styrenes: Facile Synthesis of Cyclopentenyl Phosphoranes

Vijay Nair; Ani Deepthi; P. B. Beneesh; Suresh Eringathodi

doi:10.1055/s-2006-926423

PAPER

A Novel Three-Component Reaction of Triphenylphosphine, DMAD, and Electron-Deficient Styrenes: Facile Synthesis of Cyclopentenyl Phosphoranes

Vijay Nair*^a, Ani Deepthi^a, P. B. Beneesh^a, Suresh Eringathodi^b
^a Organic Chemistry Division, Regional Research Laboratory (CSIR), Trivandrum 695019, India
^b Analytical Science Discipline, Central Salt and Marine Chemicals Research Institute, Bhavnagar 364002, India
Fax: +91(471)2491712; e-Mail: vijaynair_2001@yahoo.com;

Abstract

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Abstract

The zwitterion formed from triphenylphosphine and DMAD adds to electron-deficient styrenes to form stable cyclopentenyl phosphoranes. This is the first example of such a zwitterion in which the phosphine is incorporated into the product

Key words

triphenylphosphine - dimethyl acetylenedicarboxylate - zwitterions - electron-deficient styrenes - phosphoranes

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Referenzen

References

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