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DOI: 10.1055/a-1492-4943
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Perspectives on Organoheteroatom and Organometallic Chemistry

Recent Advances and the Prospect of Hypervalent Iodine Chemistry

Xiao-Guang Yang
,
Ze-Nan Hu
,
Meng-Cheng Jia
,
Feng-Huan Du
,
Chi Zhang
This work was financially supported by the National Natural Science Foundation of China (21772096 and 22071116) and the National Key Research and Development Program of China (2017YFD020030202).


Dedicated to the College of Chemistry, Nankai University, on its 100th anniversary

Abstract

Nowadays, hypervalent iodine chemistry has remarkably advanced in parallel with the emergence of novel hypervalent iodine reagents. Hypervalent iodine reagents, due to their outstanding characteristics including rich reactivities, excellent chemoselectivity, stability, and environmental friendliness, are becoming more and more popular in the synthetic organic chemistry. In this Account, a number of recent elegant research works and our perspective on the future of hypervalent iodine chemistry is presented.

1 Introduction

2 Recent Advances and Discussion

2.1 Novel Reactivities of Hypervalent Iodine Reagents

2.2 Atom-Economical Reactions Promoted by Hypervalent Iodine Reagents

2.3 Other Applications of Hypervalent Iodine Reagents

2.4 The Applications of DFT Calculations in Elucidating Reaction Mechanism Involving Hypervalent Iodine Reagents

3 Outlook and Conclusion



Publication History

Received: 31 March 2021

Accepted after revision: 27 April 2021

Publication Date:
27 April 2021 (online)

© 2021. Thieme. All rights reserved

Georg Thieme Verlag KG
Rüdigerstraße 14, 70469 Stuttgart, Germany

 
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