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Synthesis 2022; 54(10): 2487-2493
DOI: 10.1055/a-1730-8186
DOI: 10.1055/a-1730-8186
paper
Room Temperature, Metal-Free, Regioselective Arylselenation of Anilines Using Diselenides as Selenium Source
The Council of Scientific and Industrial Research [No. 02(0341)/18/EMR-II] and SERB-DST, New Delhi (CRG/2020/003634).
This work is dedicated to Professor Deevi Basavaiah (University of Hyderabad) on his 71st birthday.
Abstract
A metal-free direct C–H selenation of aniline derivatives via an iodine-catalyzed C–Se bond formation using diselenides as a selenium source at ambient temperature is described. A variety of aniline derivatives underwent regioselective C–H selenation with different diselenides to afford the corresponding aryl selenoethers in good to excellent yields.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1730-8186.
- Supporting Information
Publication History
Received: 03 August 2021
Accepted after revision: 04 January 2022
Accepted Manuscript online:
04 January 2022
Article published online:
08 March 2022
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