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Synthesis 2022; 54(11): 2669-2676
DOI: 10.1055/a-1739-5042
DOI: 10.1055/a-1739-5042
paper
Synthesis of Seleno Oxindoles via Iodine-Induced Radical Cyclization of N-Arylacrylamides with Diorganyl Diselenides
This work was financially supported by the Hunan Province Science Foundation for Youths (2020JJ4035) and Double First-Class Construction Project of Hunan Agricultural University (SYL2019064, SYL2019063), the Basic Research Foundation of China Tobacco Yunnan Industrial Corporation (11700167), Outstanding postdoctoral Innovative Talents Program of Science and Technology Innovation Talents Program of Hunan Province (2021RC2079) and Foundation of Hunan Provincial Key Laboratory of Crop Germplasm Innovation and Resource Utilization (18KFXM07).
Abstract
A mild, radical cascade cyclization of N-arylacrylamides with diselenides for the preparation of oxindoles via iodine oxidation is disclosed that provides an environmentally friendly process for the construction of C–Se bonds. Twenty-five examples of N-arylacrylamide substrates were investigated, and excellent yields were achieved. The tandem cyclization of acrylamide with diphenyl disulfide was also applicable under the same conditions.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1739-5042.
- Supporting Information
Publication History
Received: 03 November 2021
Accepted: 13 January 2022
Accepted Manuscript online:
13 January 2022
Article published online:
17 March 2022
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