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Synthesis 2023; 55(16): 2537-2542
DOI: 10.1055/a-2069-4665
paper
Special Issue Honoring Prof. Guoqiang Lin’s Contributions to Organic Chemistry

Palladium/Azaphos-Catalyzed Asymmetric Suzuki–Miyaura Coupling

Yanxin Jiang
a   Department of Chemistry, Hong Kong Baptist University, Kowloon, Hong Kong, P. R. of China
,
Kwai Wun Cheng
a   Department of Chemistry, Hong Kong Baptist University, Kowloon, Hong Kong, P. R. of China
,
Haoyang Zhang
b   Department of Chemistry, Southern University of Science and Technology, Shenzhen, Guangdong, 518055, P. R. of China
,
Zhiping Yang∗
a   Department of Chemistry, Hong Kong Baptist University, Kowloon, Hong Kong, P. R. of China
,
Jun Wang  (Joelle)∗
a   Department of Chemistry, Hong Kong Baptist University, Kowloon, Hong Kong, P. R. of China
› Author AffiliationsWe gratefully acknowledge the Research Grants Council of Hong Kong (GRF 12303422) and HKBU RC-Tier 2 Start-up Grant for financial support.
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Dedicated to Professor Guo-Qiang Lin on the occasion of his 80th birthday

Abstract

A palladium-catalyzed asymmetric Suzuki–Miyaura coupling is described with a unique monophosphine ligand, Azaphos. This method provides a new ligand framework that could be used in asymmetric Suzuki–Miyaura coupling reactions to prepare the axially chiral compounds.

Key words

Suzuki–Miyaura coupling - azaphos - palladium - axial chirality

Supporting Information

    Supporting information for this article is available online at https://doi.org/10.1055/a-2069-4665.
  • Supporting Information


Publication History

Received: 23 February 2023

Accepted after revision: 05 April 2023

Accepted Manuscript online:
05 April 2023

Article published online:
04 May 2023

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