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Synlett 2023; 34(18): 2110-2116
DOI: 10.1055/a-2126-1835
DOI: 10.1055/a-2126-1835
new tools
Modern Boron Chemistry: 60 Years of the Matteson Reaction
Remote Steric Control for Site-Selective Synthesis
This work was supported by the Japan Society for the Promotion of Science (JSPS) KAKENHI Grant-in-Aid for Transformative Research Areas No. 22H05384 (L.I.) (Digi-TOS) and Grant-in-Aid for Scientific Research (B) No. 22H02125 (S.A.).
Abstract
Control of site selectivity for organic synthesis in general, and for transition-metal-catalyzed C–H functionalization in particular, is an important and challenging task. Steric interactions have been widely used to control reaction selectivity, but these strategies are largely limited to proximity sites. Recently, control of site selectivity through remote steric interactions has emerged as an attractive strategy that can enable selective reactions at distal sites from a steric marker. This review will cover recent developments in this area, with a focus on borylation reactions and transition-metal-catalyzed C–H activation.
Key words
steric control - site selectivity - remote control - C–H activation - transition-metal catalysisPublikationsverlauf
Eingereicht: 30. Mai 2023
Angenommen nach Revision: 10. Juli 2023
Accepted Manuscript online:
10. Juli 2023
Artikel online veröffentlicht:
23. August 2023
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