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Synthesis
DOI: 10.1055/a-2733-1592
Paper

Electrochemically Catalyzed Decarboxylative Borylation of (Hetero)Aryl Carboxylic Acids

Authors

  • Yan Tian

    1   School of Inspection, Testing, and Certification, Changzhou Vocational Institute of Engineering, Changzhou, China (Ringgold ID: RIN164388)
    2   Chemical Engineering and Biotechnology, Donghua University, Shanghai, China (Ringgold ID: RIN12475)

  • Yingchao Li

    3   School of Inspection, Testing and Certification, Changzhou Vocational Institute of Engineering, Changzhou, China (Ringgold ID: RIN164388)

  • Yucan He

    3   School of Inspection, Testing and Certification, Changzhou Vocational Institute of Engineering, Changzhou, China (Ringgold ID: RIN164388)

  • Zu Xu

    3   School of Inspection, Testing and Certification, Changzhou Vocational Institute of Engineering, Changzhou, China (Ringgold ID: RIN164388)

  • Yulu Yuan

    3   School of Inspection, Testing and Certification, Changzhou Vocational Institute of Engineering, Changzhou, China (Ringgold ID: RIN164388)

  • Bo Xu

    4   College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai, China (Ringgold ID: RIN12475)

  • Xianqiang Kong

    5   School of Chemical Engineering and Materials, Changzhou Institute of Technology, Changzhou, China (Ringgold ID: RIN164387)

Gefördert durch: National Natural Science Foundation of China 22202021,22372015
Gefördert durch: Changzhou Vocational Institute of Engineering 11130900122004
Gefördert durch: The Qinglan Project
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Preview

A straightforward and efficient electrochemical method for the decarboxylative borylation of (hetero)aryl carboxylic acids has been outlined. This metal-/base-/oxidant-free strategy enables efficient access to arylboronate esters, demonstrating broad substrate scope (20 examples) with yields up to 62% while maintaining exceptional atom- and step-economy.



Publikationsverlauf

Eingereicht: 30. April 2025

Angenommen nach Revision: 27. Oktober 2025

Accepted Manuscript online:
27. Oktober 2025

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