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Synfacts 2009(8): 0876-0876
DOI: 10.1055/s-0029-1217442
DOI: 10.1055/s-0029-1217442
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Formal Nucleophilic Substitution of Bromocyclopropanes
B. K. Alnasleh, W. M. Sherrill, M. Rubina, J. Banning, M. Rubin*
The University of Kansas, Lawrence, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
23. Juli 2009 (online)
Significance
Further to previous research concerning 1,2-dehydrohalogenations of bromocyclopropanes (Tetrahedron 2008, 64, 8610; Synthesis 2009, 1477), the authors now provide a diastereoselective procedure for the inter- and intramolecular formal substitution of bromocyclopropanes with oxygen- and nitrogen-based nucleophiles.