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Synfacts 2010(12): 1406-1406  
DOI: 10.1055/s-0030-1258859
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Allylation of Nitrosobenzene with Pinacol Allylboronates

Contributor(s): Paul Knochel, Andreas J. Wagner
R. E. Kyne, M. C. Ryan, L. T. Kliman, J. P. Morken*
Boston College, Chestnut Hill, USA
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Publikationsdatum:
22. November 2010 (online)

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Significance

The addition of nitrosobenzene to pinacol allyl boronates leads to oxidative cleavage of the carbon-boron bond with a simultaneous ­rearrangement of the alkene substrate. The final reaction products are secondary allylic alcohols.