Highly Diastereoselective Iron-Mediated C(sp²)-C(sp³)
Cross-Couplings

doi:10.1055/s-0030-1260394

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Synfacts 2011(6): 0652-0652
DOI: 10.1055/s-0030-1260394

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

Highly Diastereoselective Iron-Mediated C(sp^²)-C(sp^³) Cross-Couplings

Contributor(s): Mark Lautens, Patrick T. Franke
A. K. Steib, T. Thaler, K. Komeyama, P. Mayer, P. Knochel*
Ludwig-Maximilians-Universität München, Germany

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Publikationsdatum:
19. Mai 2011 (online)

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Significance

Knochel and co-workers described a new iron-mediated C(sp^²)-C(sp^³) coupling of 2-iodocycloalcohol derivatives with aryl Grignard reagents. This stereoconvergent reaction affords the thermodynamically more stable arylated products.

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Highly Diastereoselective Iron-Mediated C(sp²)-C(sp³) Cross-Couplings

Publikationsverlauf

Significance

Highly Diastereoselective Iron-Mediated C(sp^²)-C(sp^³) Cross-Couplings