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Synthesis 2012; 44(11): 1693-1699
DOI: 10.1055/s-0031-1290952
DOI: 10.1055/s-0031-1290952
paper
IBX/I2-Mediated Reaction of Sodium Arenesulfinates with Alkenes: Facile Synthesis of β-Keto Sulfones
Further Information
Publication History
Received: 13 February 2012
Accepted after revision: 19 March 2012
Publication Date:
27 April 2012 (online)
Abstract
A direct synthesis of β-keto sulfones from alkenes is described. A combination of o-iodoxybenzoic acid/iodine (IBX/I2) was found to mediate the reactions of alkenes with arenesulfinates to yield β-keto sulfones in good yields via a one-pot reaction.
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