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Synthesis 2012; 44(18): 2938-2946
DOI: 10.1055/s-0032-1316764
DOI: 10.1055/s-0032-1316764
paper
Atom-Economic, Metal- and Halogen-Free Synthesis of Podands: α,ω-Diphosphines and Their Chalcogenides Separated by Alkane Diol Spacers
Further Information
Publication History
Received: 05 June 2012
Accepted after revision: 08 July 2012
Publication Date:
08 August 2012 (online)
Abstract
Secondary phosphines and phosphine chalcogenides add to the divinyl ether of α,ω-alkane diols regio- and chemoselectively under free-radical conditions (UV irradiation or AIBN, 2:1 reactants molar ratio) to give anti-Markovnikov diadducts in good to excellent yields (65–98%).
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