Palladium-Catalyzed Synthesis of Mono- and Diphosphorylated 1,10-Phenanthrolines

Alexandre Mitrofanov; Alla Bessmertnykh Lemeune; Christine Stern; Roger Guilard; Nataliya Gulyukina; Irina Beletskaya

doi:10.1055/s-0032-1317517

Synthesis, Table of Contents

Synthesis 2012; 44(24): 3805-3810
DOI: 10.1055/s-0032-1317517

paper

Palladium-Catalyzed Synthesis of Mono- and Diphosphorylated 1,10-Phenanthrolines

Alexandre Mitrofanov

^aInstitut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB) - UMR 6302 CNRS, 9 Av. Alain Savary, 21000 Dijon, France Phone: +33(3)80396117 Email: Roger.Guilard@u-bourgogne.fr

^bDepartment of Chemistry, Moscow State University, Leninskie Gory, GSP-1, 119991 Moscow, Russian Federation

,

Alla Bessmertnykh Lemeune

^aInstitut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB) - UMR 6302 CNRS, 9 Av. Alain Savary, 21000 Dijon, France Phone: +33(3)80396117 Email: Roger.Guilard@u-bourgogne.fr

,

Christine Stern

^aInstitut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB) - UMR 6302 CNRS, 9 Av. Alain Savary, 21000 Dijon, France Phone: +33(3)80396117 Email: Roger.Guilard@u-bourgogne.fr

,

Roger Guilard*

^aInstitut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB) - UMR 6302 CNRS, 9 Av. Alain Savary, 21000 Dijon, France Phone: +33(3)80396117 Email: Roger.Guilard@u-bourgogne.fr

,

Nataliya Gulyukina

^bDepartment of Chemistry, Moscow State University, Leninskie Gory, GSP-1, 119991 Moscow, Russian Federation

^cFrumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky Pr. 31, 119991 Moscow, Russian Federation Fax: +7(495)9393618 Email: beletska@org.chem.msu.ru

,

Irina Beletskaya*

^bDepartment of Chemistry, Moscow State University, Leninskie Gory, GSP-1, 119991 Moscow, Russian Federation

^cFrumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky Pr. 31, 119991 Moscow, Russian Federation Fax: +7(495)9393618 Email: beletska@org.chem.msu.ru

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Abstract

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Abstract

A general protocol for the coupling of mono- and dihalo-1,10-phenanthrolines with diethyl phosphite is reported. This reaction proceeds smoothly in the presence of a Pd(OAc)₂/dppf catalytic system and triethylamine as a base.

Key words

catalysis - cross-coupling - palladium - heterocycles - phosphorylation

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References

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