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Synthesis 2014; 46(05): 607-612
DOI: 10.1055/s-0033-1338578
DOI: 10.1055/s-0033-1338578
paper
Copper/Silver-Mediated Decarboxylative Trifluoromethylation of α,β-Unsaturated Carboxylic Acids with CF3SO2Na
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Publication History
Received: 18 August 2013
Accepted after revision: 29 November 2013
Publication Date:
17 December 2013 (online)
Abstract
A copper/silver-catalyzed decarboxylative trifluoromethylation of α,β-unsaturated carboxylic acids with CF3SO2Na was performed under relatively mild conditions. The reaction shows high E/Z selectivity and wide substrate tolerance. Ag2CO3 plays an important role in promoting the decarboxylation process.
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