Synthesis 2013; 45(15): 2150-2154
DOI: 10.1055/s-0033-1338924
paper
© Georg Thieme Verlag Stuttgart · New York

Synthesis of Novel Octahedral Silicon Compounds; Synthesis of Bis[3-(1-{[aryl(hydroxy)methylene]hydrazinylidene}ethyl)-6-methyl-2-oxo-2H-pyran-4-olato-N,O,O′]silicon(IV)

Sotiria Karamouzi
a  Laboratory of Organic Chemistry, Department of Chemical Engineering, University of Thessaloniki, Thessaloniki 54124, Greece   Fax: +30(231)0996253   Email: kotali@eng.auth.gr
,
Anna Maniadaki
a  Laboratory of Organic Chemistry, Department of Chemical Engineering, University of Thessaloniki, Thessaloniki 54124, Greece   Fax: +30(231)0996253   Email: kotali@eng.auth.gr
,
Despina A. Nasiopoulou
a  Laboratory of Organic Chemistry, Department of Chemical Engineering, University of Thessaloniki, Thessaloniki 54124, Greece   Fax: +30(231)0996253   Email: kotali@eng.auth.gr
,
Elvira Kotali
a  Laboratory of Organic Chemistry, Department of Chemical Engineering, University of Thessaloniki, Thessaloniki 54124, Greece   Fax: +30(231)0996253   Email: kotali@eng.auth.gr
,
Antigoni Kotali*
a  Laboratory of Organic Chemistry, Department of Chemical Engineering, University of Thessaloniki, Thessaloniki 54124, Greece   Fax: +30(231)0996253   Email: kotali@eng.auth.gr
,
Philip A. Harris
b  GlaxoSmithKline, 1250 South Collegeville Road, P.O. Box 5089, Collegeville, PA 19426-0989, USA
,
James Raftery
c  The School of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, UK
,
John A. Joule
c  The School of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, UK
› Author Affiliations
Further Information

Publication History

Received: 13 December 2012

Accepted after revision: 06 May 2013

Publication Date:
24 June 2013 (online)


Abstract

The synthesis of new silicon compounds is reported via the cyclization of dehydroacetic acid N-acylhydrazones with silicon tetraacetate. The procedure involves formation of new octahedral hexacoordinated silicon structures.

Supporting Information

 
  • References

  • 1 Voronkov MG, Trofimova OM, Bolgova YI, Chernov NF. Russ. Chem. Rev. 2007; 76: 825
  • 2 Holmes RR. Chem. Rev. 1996; 96: 927
  • 3 Xiang Y, Fu C, Breiding T, Sasmal PK, Liu H, Shen Q, Harms K, Zhang L, Meggers E. Chem. Commun. 2012; 48: 7131
  • 4 Cheunga Y.-S, Nga C.-Y, Chiub C.-W, Li W.-K. THEOCHEM 2003; 623: 1
    • 5a Boehme U, Guenther B. Inorg. Chem. Commun. 2007; 10: 482
    • 5b Boehme U, Wiesner S, Guenther B. Inorg. Chem. Commun. 2006; 9: 806
  • 6 Seiler O, Burschka C, Metz S, Penka M, Tacke R. Chem. Eur. J. 2005; 11: 7379
  • 7 Warncke G, Boehme U, Guenther B, Kronstein M. Polyhedron 2012; 47: 46
  • 8 Kaempfe A, Kroke E, Wagler J. Eur. J. Inorg. Chem. 2009; 8: 1027
    • 9a Kotali A, Lafazanis IS, Harris PA. Tetrahedron Lett. 2007; 48: 7871
    • 9b Kotali A, Lafazanis IS, Harris PA. Synthesis 2008; 836
    • 9c Kotali A, Lafazanis IS, Harris PA. Synth. Commun. 2008; 38: 3996
    • 9d Kotali A, Nasiopoulou DA, Harris PA, Helliwell M, Joule JA. Tetrahedron 2012; 68: 761
    • 10a Kotali A. ARKIVOC 2009; (i): 81
    • 10b Kotali A, Kotali E, Lafazanis IS, Harris PA. Curr. Org. Synth. 2010; 7: 62
    • 10c Helliwell M, Nasiopoulou DA, Kotali A, Harris PA, Joule JA. Acta Crystallogr., Sect. E 2011; 67: o1014
    • 11a Girshberg O, Kalikhman I, Stalke D, Kost D. THEOCHEM 2003; 661: 259
    • 11b Kost D, Kalikhmann I. Acc. Chem. Res. 2009; 42: 303
  • 12 Chitrapriya N, Mahalingam V, Zeller M, Jayabalan R, Swaminathan K, Natarajan K. Polyhedron 2008; 27: 939
  • 13 Chen X, Berger A, Ge M, Hopfe S, Dai N, Gösele U, Schlecht S, Steinhart M. Chem. Mater. 2011; 23: 3129
  • 14 Singh RV, Tandon JP. Indian J. Chem., Sect. A 1980; 19: 602
  • 15 Chavan SN, Inamdar VE, Sunthankar SV. Indian J. Chem. 1975; 13: 808
  • 16 Hawaldar VS, Sunthankar SV. Indian J. Text. Res. 1980; 5: 20
  • 17 Abe Y, Nahgao Y, Miosono T. Nippon Kagaku Kaishi 1984; 1128
  • 18 Schlecht S, Frank W, Braun M. Phosphorus, Sulfur Silicon Relat. Elem. 2011; 186: 1585
  • 19 Weinhold F, West R. Organometallics 2011; 30: 5815
  • 20 Rollas S, Küçükgüzel G. Molecules 2007; 12: 1910