Facile Synthesis of Rubicenes by Scholl Reaction

Masahiko Kawamura; Eiji Tsurumaki; Shinji Toyota

doi:10.1055/s-0036-1588570

Synthesis, Inhaltsverzeichnis

Synthesis 2018; 50(01): 134-138
DOI: 10.1055/s-0036-1588570

paper

Facile Synthesis of Rubicenes by Scholl Reaction

Autor*innen

Masahiko Kawamura

Department of Chemistry, School of Science, Tokyo Institute of Technology, 2–12–1 Ookayama, Meguro-ku, Tokyo 152-8551, Japan eMail: stoyota@cms.titech.ac.jp
Eiji Tsurumaki

Department of Chemistry, School of Science, Tokyo Institute of Technology, 2–12–1 Ookayama, Meguro-ku, Tokyo 152-8551, Japan eMail: stoyota@cms.titech.ac.jp
Shinji Toyota*

Department of Chemistry, School of Science, Tokyo Institute of Technology, 2–12–1 Ookayama, Meguro-ku, Tokyo 152-8551, Japan eMail: stoyota@cms.titech.ac.jp

Abstract

Alle Artikel dieser Rubrik

Abstract

The treatment of 9,10-diphenylanthracenes with DDQ in the presence of TfOH readily gave the corresponding rubicene derivatives in good yields. The effects of oxidant, acid, substituent, and other conditions are discussed. This protocol involving the Scholl reaction is convenient for the preparation of some rubicene derivatives from conventional starting materials.

Key words

rubicene - Scholl reaction - DDQ - oxidation - arenes

Volltext

Referenzen

References

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Zusatzmaterial

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