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Synthesis 2018; 50(01): 134-138
DOI: 10.1055/s-0036-1588570
DOI: 10.1055/s-0036-1588570
paper
Facile Synthesis of Rubicenes by Scholl Reaction
This work was partly supported by JSPS KAKENHI for Scientific Research (C) (26410060).Weitere Informationen
Publikationsverlauf
Received: 26. Juli 2017
Accepted after revision: 28. August 2017
Publikationsdatum:
25. September 2017 (online)
Abstract
The treatment of 9,10-diphenylanthracenes with DDQ in the presence of TfOH readily gave the corresponding rubicene derivatives in good yields. The effects of oxidant, acid, substituent, and other conditions are discussed. This protocol involving the Scholl reaction is convenient for the preparation of some rubicene derivatives from conventional starting materials.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0036-1588570.
- Supporting Information
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