Synthesis 2017; 49(17): 4035-4044
DOI: 10.1055/s-0036-1589042
paper
© Georg Thieme Verlag Stuttgart · New York

Synthesis of N-Sulfonyl Ynamido-Phosphonates: Valuable Partners for Cycloadditions

Vincent Perez
Méthodologie, Synthèse et Molécules Thérapeutiques, ICMMO, UMR CNRS 8182, Bât. 410, Université Paris-Sud 15, rue Georges Clemenceau, 91405 Orsay Cedex, France   Email: [email protected]
,
Antoine Fadel
Méthodologie, Synthèse et Molécules Thérapeutiques, ICMMO, UMR CNRS 8182, Bât. 410, Université Paris-Sud 15, rue Georges Clemenceau, 91405 Orsay Cedex, France   Email: [email protected]
,
Méthodologie, Synthèse et Molécules Thérapeutiques, ICMMO, UMR CNRS 8182, Bât. 410, Université Paris-Sud 15, rue Georges Clemenceau, 91405 Orsay Cedex, France   Email: [email protected]
› Author Affiliations
Further Information

Publication History

Received: 24 March 2017

Accepted after revision: 03 May 2017

Publication Date:
20 June 2017 (online)


Abstract

N-Sulfonyl ynamido-phosphonates were prepared from sulfonamides and bromo alkynylphosphonates through a direct copper-catalyzed coupling reaction. The substrates were obtained in good to excellent yields. The latter are valuable partners to react with nitrile-oxides­ to form isoxazoles in good yields and with an exclusive regio­selectivity.

Supporting Information

 
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