Mn(II)-Catalyzed N-Acylation of Amines

Juan Ma; Jingyu Zhang; Hang Gong

doi:10.1055/s-0037-1610267

Synthesis, Table of Contents

Synthesis 2019; 51(03): 693-703
DOI: 10.1055/s-0037-1610267

paper

Mn(II)-Catalyzed N-Acylation of Amines

Juan Ma

,

Jingyu Zhang

,

Hang Gong*

The Key Laboratory for Green Organic Synthesis and Application of Hunan Province; The Key Laboratory of Environmentally Friendly Chemistry and Application of the Ministry of Education College of Chemistry, Xiangtan University, Xiangtan 411105, P. R of China Email: hgong@xtu.edu.cn

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Abstract

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Abstract

A practical protocol has been developed here for the Mn(II)-catalyzed N-acylation of amines with high yields using N,N-dimethylformamide and other amides as the carbonyl source. The protocol is simple, does not require any acid, base, ligand, or other additives, and encompasses a broad substrate scope for primary, secondary, and heterocyclic amines.

Key words

synthetic methodology - N-acylation - manganese - amide - catalytic reaction

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References

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