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Synthesis 2021; 53(08): 1489-1494
DOI: 10.1055/s-0040-1705961
DOI: 10.1055/s-0040-1705961
paper
Nickel-Catalyzed Reductive Allylation of Aldehydes with Allyl Acetates
The work was financially supported by the OGAWA Science and Technology Foundation (EY) and a Ministry of Education, Culture, Sports, Science, and Technology (MEXT) Grant-in-Aid for Young Scientists (Grant Number 18K14871) (to E.Y.).
Abstract
Carbonyl allylation reactions constitute an important step in the formation of carbon–carbon reactions, and involve various related reactions that chiefly use allylmetal reagents. This report presents a nickel-catalyzed carbonyl allylation reaction using allyl acetate, which produces homoallyl alcohols in moderate to good yields, as an efficient methodology under reductive coupling conditions.
Key words
reductive allylation - nickel complex - allyl acetate - carbonyl addition - transition-metal catalysisSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0040-1705961.
- Supporting Information
Publication History
Received: 01 September 2020
Accepted after revision: 01 October 2020
Article published online:
02 December 2020
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For reviews on the Grignard reaction, see:
For reviews on allyl Grignard reagents, see:
For selected recent examples of Krische allylation in natural product synthesis, see:
For reviews on reductive coupling, see:
For selected examples of the reductive coupling reaction, see: