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Synthesis 2020; 52(19): 2833-2840
DOI: 10.1055/s-0040-1707166
DOI: 10.1055/s-0040-1707166
paper
Stereoselective Rhodium-Catalyzed Isomerization of Stereoisomeric Mixtures of Arylalkenes
Financial supports from the National Natural Science Foundation of China (Grant No. 21702056, 21971059 and 21901068), the National Program for Thousand Young Talents of China, and the Fundamental Research Funds for the Central Universities are greatly appreciated.
Weitere Informationen
Publikationsverlauf
Received: 29. Mai 2020
Accepted after revision: 02. Juni 2020
Publikationsdatum:
06. Juli 2020 (online)
Abstract
A new efficient method for the synthesis of a high ratio of E-alkenes from E/Z mixtures of alkenes with B2pin2 in the presence of a rhodium catalyst is described. This reaction features mild reaction conditions, broad functional group tolerance, and highly great application potential.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0040-1707166.
- Supporting Information
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