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Synlett 2023; 34(12): 1477-1481
DOI: 10.1055/s-0042-1751469
DOI: 10.1055/s-0042-1751469
cluster
Special Issue Honoring Masahiro Murakami’s Contributions to Science
Electrochemically Controlled Ruthenium-Catalyzed Olefin Metathesis
This work was supported by the National Science Foundation (Grant No. 2102672). The authors acknowledge the use of facilities and instrumentation supported by the NSF through Columbia University, Columbia Nano Initiative, and the Materials Research Science and Engineering Center (DMR-2011738).
Abstract
The development of a system to electrochemically control ruthenium-catalyzed olefin metathesis is reported. Catalyzed by a commercially-available bis-NHC Ru complex, this system displays a broad substrate scope with very short reaction times, as well as excellent levels of temporal control over metathesis with only electricity as a stimulus.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0042-1751469.
- Supporting Information
Publication History
Received: 31 March 2023
Accepted after revision: 16 May 2023
Article published online:
28 June 2023
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