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Synthesis 1990; 1990(2): 147-148
DOI: 10.1055/s-1990-26816
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Non-ligated Nickel Chloride-Catalyzed Cross-Coupling of Aromatic Grignard Reagents with Aryl Halides

Yoshiharu Ikoma* , Fumio Taya, Ei-ichi Ozaki, Shigeki Higuchi, Yoshitake Naoi, Kiyomi Fuji-i
  • *Yuki Gosei Kogyo Co. Ltd., The Tokyo Research Laboratory, Sakashita. Itabashi-ku, Tokyo 174, Japan
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Publication Date:
17 September 2002 (online)

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The reaction between aryl Grignard reagents and aryl halides in the presence of non-ligated nickel(II) chloride affords the cross-coupling products in high yields (60-98%).