PDF herunterladen
Synlett 1991; 1991(9): 659-660
DOI: 10.1055/s-1991-20832
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Manganese(III)-Promoted Free-Radical Addition of Dimethyl Bromomalonate to Olefins Using an Electrochemical Regeneration Procedure

J. Y. Nédélec* , K. Nohair
  • *C. N. R. S., Laboratoire d'Electrochimie Catalyse et Synthèse Organique, UMR 28, 2 rue H. Dunant, F-94320 Thiais, France
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
07. März 2002 (online)

  als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

The free-radical chain addition reaction of dimethyl bromomalonate onto olefins can be easily initiated by electrochemically in situ generated manganic salt used in catalytic amount, to give the 1:1 adduct (dimethyl 2-bromoalkylmalonates) in high chemical and faradaic yield at or near room temperature. The method illustrated here offers an interesting approach to carry out free-radical reactions under very simple reaction conditions.

      >