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Synthesis 1991; 1991(2): 147-149
DOI: 10.1055/s-1991-26400
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Palladium-Catalyzed Hetero-Cope Rearrangement of Alkyl Allyl N-Aryldithiocarbonimidates

J. Garin* , E. Meléndez, F. L. Merchán, T. Tejero, S. Uriel, J. Ayestarán
  • *Departamento de Quimica Orgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, E-50009 Zaragoza, Spain
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Publication Date:
27 September 2002 (online)

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Palladium-catalyzed [3,3] sigmatropic rearrangement of allyl methyl N-aryldithiocarbonimidates affords methyl N-allyl-N-aryldithiocarbamates. Very high yields of rearranged products can be obtained depending on the substitution pattern of the allyl group.

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