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Synlett 1993; 1993(2): 145-147
DOI: 10.1055/s-1993-22382
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Synthesis of Homoallylic Alcohols via Palladium-Catalyzed Cross-Coupling of Vinylic Oxetanes and Aryl and Vinylic Iodides or Triflates

Richard C. Larock* , Shuji Ding, Chi Tu
  • *Department of Chemistry, Iowa State University, Ames, Iowa 50011, USA
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Publikationsdatum:
19. März 2002 (online)

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Palladium acetate in the presence of n-Bu4NCl or LiCl, NaO2CH and i-Pr2NEt in N,N-dimethylacetamide catalyzes the cross-coupling of vinylic oxetanes and aryl and vinylic iodides or vinylic triflates to provide good yields of the corresponding 5-aryl-3-alken-1-ols and 3,6-alkadien-1-ols respectively.