PDF herunterladen
Synthesis 1993; 1993(3): 277-279
DOI: 10.1055/s-1993-25844
short paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Two-Carbon Chain Extension of Chiral Aldehydes via 2-Alkenylthiazoles: Synthesis of γ-Functionalized Alkanals

Alessandro Dondoni* , Pedro Merino, Jesus Orduna, Daniela Perrone
  • *Dipartimento di Chimica, Laboratorio di Chimica Organica, Università, Ferrara, Italy
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
17. September 2002 (online)

 als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

The reaction of 2-thiazolylmethylenetriphenylphosphorane (1a) in benzene with various aldehydes gives 2-alkenylthiazoles in variable E/Z ratios. Application of the thiazole-to-formyl deblocking protocol to the mixture of the olefins leads to saturated aldehyde homologues having two more carbon atoms.