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Synthesis 1993; 1993(3): 285-287
DOI: 10.1055/s-1993-25847
short paper
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Organophosphorus Compounds; 65.1 The Phospha-Ane Reaction: An Unusual Dimerization of Phosphaalkenes

Bernhard Breit* , Manfred Regitz
  • *Fachbereich Chemie der Universität Kaiserslautern, Erwin-Schrödinger-Strasse, D-6750 Kaiserslautern, Germany
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Publikationsdatum:
17. September 2002 (online)

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When the phosphaalkenes 7a-c were heated in a Schlenk pressure tube at 180-190°C they were transformed into the novel phosphaalkene dimers 8a-c possessing a modified P-silyl group via an ane reaction.