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Synthesis 1995; 1995(11): 1419-1422
DOI: 10.1055/s-1995-4113
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A Convenient and Efficient Synthesis of Polyphenylmono-, di-, and -triaminobenzenes

Yozo Miura* , Hiroyuki Oka, Masayoshi Momoki
  • *Department of Applied Chemistry, Faculty of Engineering, Osaka City University, Sumiyoshi-ku, Osaka 558, Japan, Fax +81(6)6052769; E-mail miura@a-chem.eng.osakau.ac.jp
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Publication Date:
31 December 2000 (online)

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A new convenient and efficient synthesis of polyphenylmono- and -diaminobenzenes by the palladium(0)-catalyzed cross-coupling reaction of polyhalomono- and -diaminobenzenes with phenylboronic acid is described. A synthesis of 2,4-diphenyl-1,3,5-triaminobenzene is also reported.

Pd-catalyzed cross coupling - phenylation - phenylboronic acid - polyhalomono- and -diaminobenzenes - polyphenylmono-, -di-, and -triaminobenzenes