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Synthesis 1996; 1996(9): 1122-1126
DOI: 10.1055/s-1996-4345
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Studies on the Allylic Oxidation of α,β-Unsaturated 13- to 15-Membered Ring Lactones

Leena Kaisalo, Jorma Koskimies, Tapio Hase*
  • *Department of Chemistry, Laboratory of Organic Chemistry, University of Helsinki, FIN-00014 Helsinki, Finland, Fax +358(0)19140366; E-Mail tapio.hase@helsinki.fi
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Publikationsdatum:
31. Dezember 2000 (online)

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γ-Hydroxy and γ-oxo-α,β-unsaturated 13- to 15-membered macrolides were prepared. The effect of the ring size on the allylic oxidation reaction with SeO2 is discussed.

allylic oxidation - selenium dioxide - macrolides - lactonization