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Synlett 1996; 1996(4): 337-338
DOI: 10.1055/s-1996-5439
DOI: 10.1055/s-1996-5439
letter
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Asymmetric Synthesis XXIV: Chiral Salen-Titanium Complexes-Efficient Catalysts for Asymmetric Trimethyl Silylcyanation of Benzaldehyde
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Publikationsdatum:
31. Dezember 2000 (online)
Chiral salen-titanium complex was found to be an effective catalyst for the enantioselective silylcyanation of benzaldehyde. The good enantioselectivity was obtained by using 5mol% Ti(IV)(salen) complex 2d as a catalyst.
chiral salen-titanium complex - enantioselectivity - cyanohydrin - catalytically asymmetric synthesis