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Synlett 1996; 1996(11): 1134-1136
DOI: 10.1055/s-1996-5677
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Rhodium (II)-Catalyzed Reactions of α-Aryl-α-diazo ketones. Stereoselective Synthesis of Ketoepoxides Related to anti-HIV Compounds

A. Fernández Mateos* , G. Pascual Coca, J. J. Pérez Alonso, R. Rubio González, C. Tapia Hernández
  • *Departamento de Química Orgánica, Facultad de C. Químicas, Universidad de Salamanca, Plaza de los Caídos 1-5, 37008 Salamanca, Spain, FAX: 3423294574, E-mail: afmateos@gugu.usal.es
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Publication Date:
31 December 2000 (online)

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A study of the rhodium (II)-catalyzed C-H insertion to form cyclopentanones has been carried out with α-aryl-α-diazo-α’,β’-unsaturated 6a-c and saturated 5a-e ketones.

Synthesis - limonoids - rhodium (II) - diazoketones - anti-HIV

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