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Synlett 1997; 1997(SI): 495-497
DOI: 10.1055/s-1997-6151
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Preparation of (R)-(-)-2-Methoxy-2'-(1H-tetrazol-5-yl)-1,1'-binaphthyl and (1R,2R)-(+)-1-Trimethylsilyl-2-(1H-tetrazol-5-yl)ferrocene: Optically Active Tetrazoles with Axial or Planar Chirality

Masaaki Hirose, Rie Kawai, Yoshihiro Hayakawa*
  • *Laboratory of Bioorganic Chemistry, Graduate School of Human Informatics, Nagoya University, Chikusa, Nagoya 464-01, Japan, Fax +81-52-789-4808; E-mail yoshi@info.human.nagoya-u.ac.jp
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Publication Date:
31 December 2000 (online)

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Preparation of (R)-(-)-2-methoxy-2'-(1H-tetrazol-5-yl)-1,1'-binaphthyl, and (1R, 2R)-(+)-1-trimethylsilyl-2-(1H-tetrazol-5-yl)ferrocene which are the first examples of optically active tetrazolyl compounds with axial or planar chirality, respectively, is described.

optically active tetrazole - atropisomer - 5-binaphthyl-1H-tetrazole 5-ferrocenyl-1H-tetrazole - 1,3-dipole addition

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