Monocarbamates, Derived from (S)-2-(Dibenzylamino)butane-1,4-diol, and the Influence of the Second O-Protecting Group on the Regioselectivity of Deprotonation - Application to the Synthesis of the Boletus Toxin (2S,4S)-γ-Hydroxy-norvaline

Martin Sendzik; Walter Guarnieri; Dieter Hoppe

doi:10.1055/s-1998-6100

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Synthesis 1998; 1998(9): 1287-1297
DOI: 10.1055/s-1998-6100

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© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Monocarbamates, Derived from (S)-2-(Dibenzylamino)butane-1,4-diol, and the Influence of the Second O-Protecting Group on the Regioselectivity of Deprotonation - Application to the Synthesis of the Boletus Toxin (2S,4S)-γ-Hydroxy-norvaline

Martin Sendzik^* , Walter Guarnieri, Dieter Hoppe

^*Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, D-48149 Münster, Germany; Fax +49(251)83 39772

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Publikationsdatum:
31. Dezember 2000 (online)

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stereoselective lithiation - chiral aminodiols - directed lithiation - chiral carbanion - (-)-sparteine