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Synthesis 2000; 2000(7): 911-913
DOI: 10.1055/s-2000-6287
short paper
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Catalytic Coupling of Aryl Sulfonates with sp2-Hybridized Nitrogen Nucleophiles: Palladium- and Nickel-catalyzed Synthesis of N-Aryl Sulfoximines

Carsten Bolm* , Jens P. Hildebrand, Jens Rudolph
  • *Institut für Organische Chemie der RWTH Aachen, Professor-Pirlet-Strasse 1, 52074 Aachen, Germany; Fax +49(241)8888 391; E-mail: Carsten.Bolm@oc.rwth-aachen.de
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Publication History

Publication Date:
31 December 2000 (online)

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Several sulfoximines have been arylated in good to high yield by palladium catalysis using aryl nonaflates and aryl triflates. Moreover, the successful synthesis of N-aryl sulfoximines from aryl tosylates is described using a Ni(COD)2/BINAP catalyst.

palladium - nickel - sulfoximines - cross-coupling - aryl sulfonates

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