Metal Triflate-Catalyzed One-Pot Synthesis of α-Aminophosphonates from Carbonyl Compounds in the Absence of Solvent

Habib Firouzabadi; Nasser Iranpoor; Sara Sobhani

doi:10.1055/s-2004-831251

PAPER

Metal Triflate-Catalyzed One-Pot Synthesis of α-Aminophosphonates from Carbonyl Compounds in the Absence of Solvent

Habib Firouzabadi*, Nasser Iranpoor*, Sara Sobhani
Department of Chemistry, Shiraz University, Shiraz 71454, Iran
Fax: +98(711)2280926; e-Mail: Firouzabadi@chem.susc.ac.ir; e-Mail: Iranpoor@chem.susc.ac.ir;

Abstract

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Abstract

A simple and general method has been developed for one-pot three-component synthesis of α-aminophosphonates catalyzed by several metal triflates [M(OTf)_n, M = Li, Mg, Al, Cu, Ce] in the absence of solvent in good to high yields.

Keywords

α-aminophosphonates - imines - diethyl phosphate - metal triflates - solvent free - aldehydes - ketones - amines

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References

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