Microwave-Assisted Chemoselective Cleavage of Oximes to Their Corresponding Carbonyl Compounds Using 1,3-Dichloro-5,5-dimethyl-hydantoin (DCDMH) as a New Deoximating Reagent

Ardeshir Khazaei; Abbas Amini Manesh

doi:10.1055/s-2005-869901

SHORTPAPER

Microwave-Assisted Chemoselective Cleavage of Oximes to Their Corresponding Carbonyl Compounds Using 1,3-Dichloro-5,5-dimethyl-hydantoin (DCDMH) as a New Deoximating Reagent

Ardeshir Khazaei*, Abbas Amini Manesh
Department of Chemistry, Faculty of Sciences, Bu-Ali sina University, P.O. Box 65178-4119, Hamadan, Iran
e-Mail: khazaei_1326@yahoo.com;

Abstract

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Abstract

In the presence of alkene and alcohol, oximes are converted into their parent carbonyl compounds in good yields when treated with 1,3-dichloro-5,5-dimethylhydantoin (DCDMH) (1), under microwave irradiation. The simple work-up minimizes loss of products.

Keywords

aldehyde - ketone - microwave - oxime - selective

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References

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