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Synlett 2005(13): 2115-2116
DOI: 10.1055/s-2005-872237
DOI: 10.1055/s-2005-872237
SPOTLIGHT
© Georg Thieme Verlag Stuttgart · New York
Trichloroisocyanuric Acid (TCCA)
Further Information
Publication History
Publication Date:
20 July 2005 (online)
Introduction
Trichloroisocyanuric acid (TCCA) is a stable and inexpensive industrial chemical usually used as bleaching agent and bactericide.
It has found applications in organic chemistry as a chlorinating agent or oxidant, [1] allowing thioacetalization of carbonyl compounds, conversion of alcohols to halides, carboxylic acids to acid chlorides, alkenes to chloroethers, N-nitrosation of N,N-dialkylamines, selective mononitration of phenols, oxidation of alcohols to carbonyl compounds, aldehydes to methyl esters, aldoximes to nitrile oxides, thiols to disulfides, selenols to diselenides, and sulfides to sulfoxides.
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