Synthesis 2006(21): 3585-3588  
DOI: 10.1055/s-2006-942513
PAPER
© Georg Thieme Verlag Stuttgart · New York

Preparation and Allylation of Enamides and Enecarbamates Generated via Iron(0) Reduction of Oximes and Derivatives

Cuixiang Sun, Steven M. Weinreb*
Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, USA
e-Mail: smw@chem.psu.edu;
Further Information

Publication History

Received 30 March 2006
Publication Date:
25 July 2006 (online)

Abstract

Reductive acylation of oximes and oxime carbonates can be effected with iron powder in the presence of an acid chloride or a chloroformate to produce enamides or enecarbamates.

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