A Novel Method for the Synthesis of Bis(1-diethoxyphosphorylalkyl)amines from Diimines

Babak Kaboudin; Ehsan Jafari

doi:10.1055/s-2006-942541

PAPER

A Novel Method for the Synthesis of Bis(1-diethoxyphosphorylalkyl)amines from Diimines

Babak Kaboudin*, Ehsan Jafari
Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Gava Zang, Zanjan 45195-1159, Iran
Fax: +98(241)4249023; e-Mail: kaboudin@iasbs.ac.ir;

Abstract

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Abstract

A novel and convenient method for the synthesis of bis(1-diethoxyphosphorylalkyl) amines has been developed. As described below, treatment of aromatic diimines with diethyl phosphite in the presence of chlorotrimethylsilane gave bis(1-diethoxyphosphorylalkyl)amines. This method is easy, rapid, and good-yielding for the synthesis of bis(1-diethoxyphosphorylalkyl)amines from simple starting materials.

Key words

TMSCl - diethylphosphite - diimines - bis(1-diethoxyphosphorylalkyl)amines - addition reaction

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