PDF herunterladen
Synfacts 2006(12): 1264-1264  
DOI: 10.1055/s-2006-949491
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York

Enantioselective Conjugate Radical Addition

Contributor(s): Hisashi Yamamoto, Joshua P. Abell
S. Lee, C. J. Lim, S. Kim*, R. Subramaniam, J. Zimmerman, M. P. Sibi*
Korea Advanced Institute of Sciences and Technology, Daejeon, Korea and , North Dakota State University, Fargo, USA
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
22. November 2006 (online)

   Lizenzen und Reprints

Significance

Enantioselective radical reactions have attracted interest lately due to their ability to introduce various stable radical intermediates to electrophiles. This paper reports the radical conjugate addition to enones using a 1,4-chelating template as opposed to the more popular 1,5-chelate.