Facile Preparation of Polyfluoroalkylated Aldimines from Polyfluoroalkanoic Acids

Jun Takagi; Ryozo Takihana; Akiko Kuwano; Kenji Uneyama

doi:10.1055/s-2007-966055

PAPER

Facile Preparation of Polyfluoroalkylated Aldimines from Polyfluoroalkanoic Acids

Jun Takagi, Ryozo Takihana, Akiko Kuwano, Kenji Uneyama*
Department of Applied Chemistry, Faculty of Engineering, Okayama University, 3-1-1 Tsushimanaka, Okayama 700-8530, Japan
Fax: +81(86)2518075; e-Mail: uneyamak@cc.okayama-u.ac.jp;

Abstract

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Abstract

Polyfluoroalkylated aldimines were prepared by reducing polyfluoroalkyl imidoyl chlorides, which are readily available from polyfluoroalkanoic acids, with LTBA (lithium tri-tert-butoxyaluminum hydride).

Key words

fluorine - aldimine - imidoyl chloride - reduction - hydride

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