[3+2] Cycloaddition of Diazocarbonyl Compounds to 1,1-Dinitroethenes: Synthesis of Functionalized gem-Dinitrocyclopropanes

Olga A. Ivanova; Ekaterina M. Budynina; Elena B. Averina; Tamara S. Kuznetsova; Yurii K. Grishin; Nikolai S. Zefirov

doi:10.1055/s-2007-983727

PAPER

[3+2] Cycloaddition of Diazocarbonyl Compounds to 1,1-Dinitroethenes: Synthesis of Functionalized gem-Dinitrocyclopropanes

Olga A. Ivanova^a,b, Ekaterina M. Budynina^a, Elena B. Averina^a, Tamara S. Kuznetsova*^a,b, Yurii K. Grishin^a, Nikolai S. Zefirov^a,b
^a Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow 119992, Russian Federation
Fax: +7(495)9390290;
^b IPhaC RAS, Severnyi Proezd 1, Chernogolovka, Moscow Region 142432, Russian Federation
e-Mail: kuzn@org.chem.msu.ru;

Abstract

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Abstract

The synthesis of functionalized gem-dinitrocyclopropanes via [3+2] cycloaddition of diazocarbonyl compounds with 1,1-dinitroethenes [in some cases in the presence of Mo(CO)₆ as catalyst] has been developed.

Key words

[3+2] cycloaddition - α-diazocarbonyl compound - 1,1-dinitroethene - 1,1-dinitrocyclopropane - hexacarbonylmolybdenum

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