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Synthesis
DOI: 10.1055/a-2640-5375
DOI: 10.1055/a-2640-5375
Paper
Published as part of the Special Issue in Honor of Prof. Franziska Schoenebeck, the
2025 Women in Chemistry Award Winner
Solar Light-Assisted C–H Activation and C–C Coupling of Hindered N, N-Dimethyl-Anilines with Activated Methylene Compounds
Funding Information Ariel University is acknowledged for providing funding for this research.
Abstract
This article describes the use of dimethyl-aniline-alkyl halide charge transfer complexes as a linchpin for sunlight-initiated C–C bond formation with activated methylene compounds, including malonates, malononitriles, and 2-cyano-esters. DFT calculations shed light on charge transfer complex formation and structure as well as on the mechanism.
Keywords
Sunlight - Visible light - Charge-transfer complex - Electron donor–acceptor complex - C–C bond formationPublication History
Received: 11 May 2025
Accepted after revision: 20 June 2025
Accepted Manuscript online:
20 June 2025
Article published online:
15 August 2025
© 2025. Thieme. All rights reserved.
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